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210512 ||| eng |
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|a 9783038976387
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|a books978-3-03897-639-4
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|a Inoue, Shigeyoshi
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|a Coordination Chemistry of Silicon
|h Elektronische Ressource
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260 |
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|b MDPI - Multidisciplinary Digital Publishing Institute
|c 2019
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300 |
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|a 1 electronic resource (225 p.)
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|a bridging silylene ligand
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|a molecular cage
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|a silanetriols
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|a germanium
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|a 2-silylpyrrolidines
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|a <i>N</i>-heterocyclic carbenes
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|a small molecule activation
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|a disilene
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|a dehydrogenative alkoxylation
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|a ?-chloro-?-hydrooligosilane
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|a <sup>29</sup>Si NMR spectroscopy
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|a siloxanes
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|a digermacyclobutadiene
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|a DFT
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|a germylene
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|a <i>N</i>-heterocyclic carbene
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|a density functional theory
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|a titanium
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|a photoreaction
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|a <i>N</i>-heterocyclic carbines
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|a silicon cluster
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|a TiO<sub>2</sub>
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|a AIM
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|a ruthenium
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|a hydrogen bonds
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|a cyclic organopolysilane
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|a bromosilylenes
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|a cluster
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|a functionalization
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|a palladium
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|a mechanistic insights
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|a isomerization
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|a excited state aromaticity
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|a salt-free
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|a reductant
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|a intermetallic bond
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|a surface modification
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|a organosilicon
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|a nanoparticle
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|a supramolecular chemistry
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|a silicon surfaces
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|a dehydrobromination
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|a disiloxane tetrols
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|a silylene
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|a silicon
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|a Photostability
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|a computational chemistry
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|a hydrogen bonding
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|a ?-electron systems
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|a germathioacid chloride
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|a main group coordination chemistry
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|a bond activation
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|a germanethione
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|a Si-Cl activation
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|a digermene
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|a isocyanide
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|a distorted coordination
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|a bonding analysis
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|a X-ray diffraction
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|a ligand-exchange reaction
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|a primary silane
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|a template
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|a molecular orbital analysis
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|a Baird's rule
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|a oxidative addition
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|a hydrido complex
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|a siliconoid
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|a dye-sensitized solar cell
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|a adsorption
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|a stereochemistry
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|a silyliumylidenes
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|a condensation
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|a subvalent compounds
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|a computation
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|a <i>N</i>-Heterocyclic tetrylene
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|a Chemistry / bicssc
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|a disilanylene polymer
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|a platinum
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|a X-ray crystallography
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|a host-guest chemistry
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|a silsesquioxanes
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|a eng
|2 ISO 639-2
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|b DOAB
|a Directory of Open Access Books
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|a Creative Commons (cc), https://creativecommons.org/licenses/by-nc-nd/4.0/
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|a 10.3390/books978-3-03897-639-4
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856 |
4 |
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|u https://directory.doabooks.org/handle/20.500.12854/44062
|z DOAB: description of the publication
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|u https://www.mdpi.com/books/pdfview/book/1156
|7 0
|x Verlag
|3 Volltext
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|a 000
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|a 540
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|a 700
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|a The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist's viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds.
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