Synthesis and Applications of New Spin Crossover Compounds

The crystal chemistry of spin crossover (SCO) behavior in coordination compounds can potentially be in association with smart materials-promising materials for applications as components of memory devices, displays, sensors and mechanical devices and, especially, actuators, such as artificial muscle...

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Bibliographic Details
Main Author: Kitazawa, Takafumi
Format: eBook
Language:English
Published: MDPI - Multidisciplinary Digital Publishing Institute 2019
Subjects:
2
N/a
1
Online Access:
Collection: Directory of Open Access Books - Collection details see MPG.ReNa
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245 0 0 |a Synthesis and Applications of New Spin Crossover Compounds  |h Elektronische Ressource 
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653 |a coordination polymer 
653 |a thermochromism 
653 |a dinuclear triple helicate 
653 |a hetero metal complex 
653 |a 2 
653 |a Fe(II) 
653 |a 57Fe Mössbauer spectroscopy 
653 |a dipyridyl-N-alkylamine ligands 
653 |a C-H···? interactions 
653 |a soft X-ray induced excited spin state trapping 
653 |a charge-transfer phase transition 
653 |a linear pentadentate ligand 
653 |a aminoxyl 
653 |a n/a 
653 |a phase transitions 
653 |a X-ray absorption spectroscopy 
653 |a LIESST effect 
653 |a spin polaron 
653 |a solvate 
653 |a solvent effects 
653 |a cobalt(II) ion 
653 |a supramolecular coordination polymer 
653 |a [Au(dmit)2]? 
653 |a paramagnetic ligand 
653 |a mosaicity 
653 |a ?-? interactions 
653 |a DFT calculation 
653 |a spin crossover 
653 |a dithiooxalato ligand 
653 |a SQUID 
653 |a spin-crossover 
653 |a Cu(II) complexes 
653 |a chiral propeller structure 
653 |a single crystal 
653 |a Fe(III) complex 
653 |a ferromagnetism 
653 |a substitution of 3d transition metal ion 
653 |a fatigability 
653 |a spin-crossover transition 
653 |a dielectric response 
653 |a ion-pair crystals 
653 |a spin transition 
653 |a iron mixed-valence complex 
653 |a low spin (LS) 
653 |a Fe(III) coordination complexes 
653 |a phase transition 
653 |a iron(II) 
653 |a magnetostructural correlations 
653 |a structural disorder 
653 |a impurity effect 
653 |a hexadentate ligand 
653 |a metal dithiolene complexes 
653 |a magnetic transition 
653 |a cobalt oxide 
653 |a 1 
653 |a supramolecular isomerism 
653 |a qsal ligand 
653 |a thermal hysteresis 
653 |a EPR spectroscopy 
653 |a switch 
653 |a hydrogen bonding 
653 |a magnetic susceptibility 
653 |a intermolecular interactions 
653 |a optical microscopy 
653 |a nitroxides 
653 |a iron(II) complexes 
653 |a spin-state crossover 
653 |a high spin (HS) 
653 |a crystal structure 
653 |a [Au(dddt)2]? 
653 |a mononuclear 
653 |a counter-anion 
653 |a coordination complexes 
653 |a high spin 
653 |a magnetic properties 
653 |a spin cross-over (SCO) 
653 |a magnetization 
653 |a Schiff base 
653 |a 2-bis(4-pyridyl)ethane 
653 |a optical conductivity spectrum 
653 |a X-ray diffraction 
653 |a spiral structure 
653 |a coordination polymers 
653 |a iron (II) 
653 |a [Fe(III)(3-OMesal2-trien)]+ 
653 |a lattice energy 
653 |a amorphous 
653 |a structure phase transition 
653 |a Fe(II) complex 
653 |a atropisomerism 
653 |a 3-triazole 
653 |a reaction diffusion 
653 |a UV-Vis spectroscopy 
653 |a crystal engineering 
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520 |a The crystal chemistry of spin crossover (SCO) behavior in coordination compounds can potentially be in association with smart materials-promising materials for applications as components of memory devices, displays, sensors and mechanical devices and, especially, actuators, such as artificial muscles. This Special Issue is devoted to various aspects of SCO and related research, comprising 18 interesting original papers on valuable and important SCO topics. Significant and fundamental scientific attention has been focused on the SCO phenomena in a wide research range of fields of fundamental chemical and physical and related sciences, containing the interdisciplinary regions of chemical and physical sciences related to the SCO phenomena. Coordination materials with bistable systems between the LS and the HS states are usually triggered by external stimuli, such as temperature, light, pressure, guest molecule inclusion, soft X-ray, and nuclear decay. Since the first Hofmann-like spin crossover (SCO) behavior in {Fe(py)2[Ni(CN)4]}n (py = pyridine) was demonstrated, this crystal chemistry motif has been frequently used to design Fe(II) SCO materials to enable determination of the correlations between structural features and magnetic properties.