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210512 ||| eng |
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|a books978-3-03928-237-1
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|a 9783039282371
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|a 9783039282364
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|a Keglevich, György
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|a Organophosphorus Chemistry 2018
|h Elektronische Ressource
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| 260 |
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|b MDPI - Multidisciplinary Digital Publishing Institute
|c 2020
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| 300 |
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|a 1 electronic resource (601 p.)
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|a hydrolysis
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|a dynamic and specific NMR parameters
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|a 1-aminoalkylphosphonic acids
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|a 1-(acylamino)alkylphosphonic acids
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|a chiral phosphines
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|a dissociation constants
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|a dialkyl H-phosphonates
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|a NMR-controlled titration
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|a ?-amidoalkylating agents
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|a Pudovik reaction
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|a transesterification
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|a bis(phosphane) palladium complex
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|a dry eye syndrome
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|a rearrangement
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|a phosphorylation
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|a DFT
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|a electrophilic substitution
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|a polycyclic compounds
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|a mechanochemistry
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|a N-acyliminium cation
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|a stability constants
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|a substitution
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|a electronic parameters
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|a synergy
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|a asymmetric catalysis
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|a 31P NMR spectra of intermediates
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|a diquafosol
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|a C-H bond activation
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|a 3-azaphospholes
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|a dinucleotides
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|a silver
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|a Diels-Alder reaction
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|a stereoselective synthesis
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|a continuous flow reactor
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|a copper
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|a O-derivatization
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|a QTAIM
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|a phosphonium salts
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|a ?-hydroxyphosphonate
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|a alcoholysis
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|a allylic alkylation
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|a amino acids
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|a 1
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|a oxidation
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|a N-acylimine
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|a metallacycle
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|a cyclo-P5
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|a weakly coordinating
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|a triple-decker
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|a denufosol
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|a NORPHOS
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|a diphosphines
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|a organophosphorus chemistry
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|a aminophosphonic acids
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|a phosphonocarboxylic acids
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|a DFT calculations
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|a molybdenum
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|a Chemistry / bicssc
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|a phosphonic acids
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|a microwave
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|a hydrolytic deacylation
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0 |
7 |
|a eng
|2 ISO 639-2
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| 989 |
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|b DOAB
|a Directory of Open Access Books
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| 500 |
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|a Creative Commons (cc), https://creativecommons.org/licenses/by-nc-nd/4.0/
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|a 10.3390/books978-3-03928-237-1
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|u https://www.mdpi.com/books/pdfview/book/2050
|7 0
|x Verlag
|3 Volltext
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4 |
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|u https://directory.doabooks.org/handle/20.500.12854/55412
|z DOAB: description of the publication
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|a 540
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|a Organophosphorus chemistry is an important discipline within organic chemistry. Phosphorus compounds, such as phosphines, trialkyl phosphites, phosphine oxides (chalcogenides), phosphonates, phosphinates and >P(O)H species, etc., may be important starting materials or intermediates in syntheses. Let us mention the Wittig reaction and the related transformations, the Arbuzov- and the Pudovik reactions, the Kabachnik-Fields condensation, the Hirao reaction, the Mitsunobu reaction, etc. Other reactions, e.g., homogeneous catalytic transformations or C-C coupling reactions involve P-ligands in transition metal (Pt, Pd, etc.) complex catalysts. The synthesis of chiral organophosphorus compounds means a continuous challenge. Methods have been elaborated for the resolution of tertiary phosphine oxides and for stereoselective organophosphorus transformations. P-heterocyclic compounds, including aromatic and bridged derivatives, P-functionalized macrocycles, dendrimers and low coordinated P-fragments, are also of interest. An important segment of organophosphorus chemistry is the pool of biologically-active compounds that are searched and used as drugs, or as plant-protecting agents. The natural analogue of P-compounds may also be mentioned. Many new phosphine oxides, phosphinates, phosphonates and phosphoric esters have been described, which may find application on a broad scale. Phase transfer catalysis, ionic liquids and detergents also have connections to phosphorus chemistry. Green chemical aspects of organophosphorus chemistry (e.g., microwave-assisted syntheses, solvent-free accomplishments, optimizations, and atom-efficient syntheses) represent a dynamically developing field. Last, but not least, theoretical approaches and computational chemistry are also a strong sub-discipline within organophosphorus chemistry.
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