Quantitative Infrared Spectroscopy for Understanding of a Condensed Matter

This book is intended to provide a course of infrared spectroscopy for quantitative analysis, covering both bulk matter and surface/interface analyses. Although the technology of Fourier transform infrared (FT-IR) spectroscopy was established many years ago, the full potential of infrared spectrosco...

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Bibliographic Details
Main Author: Hasegawa, Takeshi
Format: eBook
Language:English
Published: Tokyo Springer Japan 2017, 2017
Edition:1st ed. 2017
Subjects:
Online Access:
Collection: Springer eBooks 2005- - Collection details see MPG.ReNa
Table of Contents:
  • Infrared spectroscopy as a vibrational spectroscopy
  • Normal modes
  • Light absorption by a molecule: 1. Understanding by quantum mechanical approach
  • Selection rule of IR spectroscopy
  • Light absorption by a molecule: 2. Understanding by electrodynamical approach
  • Fundamentals of FT-IR
  • Two representations of spectra: Time- and frequency-domain representations
  • Fourier transform relationship
  • Introduction of Michaelson interferometer
  • Representative detectors
  • Sampling techniques
  • Surface analysis using FT-IR
  • Boundary conditions in electrodynamics
  • Thin-film approximation
  • Surface selection rules for surface spectroscopies
  • Chemometrics for FT-IR
  • Limitation of Beer’s law
  • Expansion of Beer’s law: CLS regression
  • Inverse Beer’s law: ILS regression
  • Mathematical expansion of CLS: PCA
  • Merge of ILS and PCA: PCR
  • Independent residual terms: PLS.