|
|
|
|
| LEADER |
02433nmm a2200337 u 4500 |
| 001 |
EB001345081 |
| 003 |
EBX01000000000000000899271 |
| 005 |
00000000000000.0 |
| 007 |
cr||||||||||||||||||||| |
| 008 |
170203 ||| eng |
| 020 |
|
|
|a 9789811007736
|
| 100 |
1 |
|
|a Hou, Ruijun
|
| 245 |
0 |
0 |
|a Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene
|h Elektronische Ressource
|c by Ruijun Hou
|
| 250 |
|
|
|a 1st ed. 2017
|
| 260 |
|
|
|a Singapore
|b Springer Nature Singapore
|c 2017, 2017
|
| 300 |
|
|
|a XII, 141 p. 83 illus., 42 illus. in color
|b online resource
|
| 505 |
0 |
|
|a Introduction -- Experimental and Theoretical Methods -- Design of Pd-Ni Bimetallic Catalyst -- Effect of Oxide Supports on Pd–Ni Bimetallic Catalysts -- Replacing Precious Metals with Carbide Catalysts -- Liquid Phase Hydrogenation of Acetylene -- Conclusion
|
| 653 |
|
|
|a Chemistry, Physical and theoretical
|
| 653 |
|
|
|a Catalysis
|
| 653 |
|
|
|a Theoretical Chemistry
|
| 653 |
|
|
|a Chemistry, Organic
|
| 653 |
|
|
|a Chemistry, Technical
|
| 653 |
|
|
|a Industrial Chemistry
|
| 653 |
|
|
|a Organic Chemistry
|
| 041 |
0 |
7 |
|a eng
|2 ISO 639-2
|
| 989 |
|
|
|b Springer
|a Springer eBooks 2005-
|
| 490 |
0 |
|
|a Springer Theses, Recognizing Outstanding Ph.D. Research
|
| 028 |
5 |
0 |
|a 10.1007/978-981-10-0773-6
|
| 856 |
4 |
0 |
|u https://doi.org/10.1007/978-981-10-0773-6?nosfx=y
|x Verlag
|3 Volltext
|
| 082 |
0 |
|
|a 541,395
|
| 520 |
|
|
|a This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.<
|