Organometallic Compounds Volume Two: The Transition Elements
to thank Messrs J. R. Sanders, W. E. Lindsell and M. G. Swanwick for helping to check the text and references and prepare indexes. Finally, I should like to thank my wife for the very considerable assis tance she has given me in the writing and production of this book. M. L. H. G. Contents Preface...
| Main Author: | |
|---|---|
| Format: | eBook |
| Language: | English |
| Published: |
Dordrecht
Springer Netherlands
1968, 1968
|
| Edition: | 1st ed. 1968 |
| Subjects: | |
| Online Access: | |
| Collection: | Springer Book Archives -2004 - Collection details see MPG.ReNa |
Table of Contents:
- to Volume Two
- Classification
- The 18-electron rule
- 1. Two-Electron Ligands
- A. Classification
- B. The preparation of olefin-transition metal complexes
- C. A molecular orbital description of the bonding in organo-metallic complexes
- D. A description of the bonding of 2-electron ligands to transition metals
- E. General comments of 2-electron ligands
- F. Particular complexes of metals with 2-electron ligands
- 2. Three-Electron Ligands
- A. Preparation of ?-enyl complexes
- B. The structure of ?-enyl complexes
- C. The ?-allyl metal bond
- D. Dynamic equilibria in allyl complexes
- E. The chemistry of particular ?-enyl complexes
- 3. Four-Electron Ligands
- A. Some differences between unconjugated and conjugated olefin ligands
- B. The bonding of 4-electron ligands to transition metals
- C. Particular studies
- 4. Five-Electron Ligands
- A. Cyclopentadienyl metal complexes
- B. ?-Cyclopentadienyl transition metal complexes
- I.1. Hydrocarbon alkyl and aryl complexes
- I.2 Transition metal-acyl complexes
- I.3. ?-Cyclopentadienyl complexes
- II. Transition metal fluorocarbon complexes
- III. Transition metal acetytides and alkynyls
- 8. Organometallic Complexes Formed From Acetylenes
- A. Monoacetylene, mononuclear complexes: acetylenes as 2-elec-tron ligands
- B. Monoacetylene binuclear complexes: acetylenes as 4-electron ligands
- C. Monoacetylene trinuclear complexes
- D. Monoacetylene tetranuclear complexes
- E. Bis-acetylene mononuclear complexes
- F. Bis-acetylene trinuclear complexes
- G. Tris-acetylene mononuclear complexes
- H. Tris-acetylene binuclear complexes
- I. Miscellaneous
- 9. The Role of Organotransition Metal Complexes in Some Catalytic Reactions
- A. Some chemistry of transition metal hydride complexes
- B. Some catalytic reactions which involve hydrogen transfer: isomerization reactions
- C. Homogeneous hydrogenation of olefins and acetylenes
- C. Cyclopentadienide transition metal complexes
- D. The bonding in mono-?-cyclopentadienyl transition metal complexes
- E. ?-Cyclopentadienyl carbonyl complexes
- F. ?-Cyclopentadienyl nitrosyl complexes
- G. Brief notes on binuclear ?-cyclopentadienyl complexes containing bridging ligands
- H. ?-Cyclopentadienyl hydride complexes
- I. ?-Cyclopentadienyl halides and oxides
- J. Other 5-electron ligands
- K. The organic chemistry of ?-cyclopentadienyl transition metal complexes
- L. Some particular reactions
- 5. Six-Electron Ligands
- A. Arene transition metal complexes
- (a) Preparation
- B. Olefin 6-electron ligands
- C. Transition metal complexes containing ?-bonded heterocyclic ligands
- 6. Seven-Electron Ligands Mixed Sandwich Complexes Related Azulene Derivatives and Cyclo-Octatetraene Complexes
- A. 7-Electron ligands.-B. Mixed sandwich complexes
- C. Metal complexes formed from azulenes
- D. Cyclo-octatetraene complexes
- 7. One-Electron Ligands
- D. Some dimerization oligomerization and polymerization reactions of olefins and acetylenes
- E. Hydroformylation and related carhonylation reactions
- F. Some general comments on the relationship between heterogeneous and homogeneous transition metal catalysts
- G. Miscellaneous
- Author
- Subject
- Crystal Structures>