Phase diagrams and ceramic processes

Ceramic products are fabricated from selected and consolidated raw materials through the application of thermal and mechanical energy. The complex connec­ tions between thermodynamics, chemical equilibria, fabrication processes, phase development, and ceramic properties define the undergraduate curr...

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Bibliographic Details
Other Authors: McHale, Anna E. (Editor)
Format: eBook
Language:English
Published: Dordrecht Springer Netherlands 1997, 1997
Edition:1st ed. 1997
Subjects:
Online Access:
Collection: Springer Book Archives -2004 - Collection details see MPG.ReNa
Table of Contents:
  • 1. Introduction
  • 1.1 Ceramic Phases and Phase Equilibria
  • 1.2 Oxides in the Environment
  • 1.3 Phase Diagrams and Ceramic Processes
  • 2. Products and Properties
  • 2.1 Electromagnetic Properties and Applications
  • 2.2 Refractory Applications
  • 3. Mass Transport for Reaction
  • 3.1 Defects in Oxides
  • 3.2 Ideal Impurity Incorporation
  • 3.3 Impurities and Defects in Real Oxides
  • 4. From Equilibrium Thermodynamics to Phase Equilibria
  • 4.1 Thermodynamic Functions and Relationships
  • 4.2 The System Definition for Chemical Equilibria
  • 4.3 State Function Measurement or Calculation
  • 4.4 Solution Properties
  • 4.5 Congruent Phase Transition
  • 4.6 Nucleation Phenomena and Transformation Kinetics
  • 5. The Phase Rule and Heterogeneous Equilibria
  • 5.1 The Gibbs Phase Rule
  • 5.2 The Phase Diagram
  • 6. One- and Two-Component System Presentations
  • 6.1 One-Component Systems
  • 6.2 Two-Component or Binary Systems
  • 6.3 Binary Phase Compatibility and Mass Balance
  • 6.4 Heterogeneous Crystallization
  • 6.5 Binary Metastability
  • 6.6 Rules for Diagram Construction
  • 7. Three or More Component Equilibria
  • 7.1 The Ternary System
  • 7.2 Ternary Phase Compatibility and Mass Balance
  • 7.3 Special Ternary Diagram Presentations
  • 7.4 Quaternary and Higher System Diagrams
  • 8. Engineered Systems and Oxide Phase Equilibria
  • 8.1 Conditions and Kinetics of Reaction
  • 8.2 Reaction in Ceramic Processing
  • 8.3 Consideration of Engineering Design
  • References
  • Suggested Exercises