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cr||||||||||||||||||||| |
| 008 |
140122 ||| eng |
| 020 |
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|a 9789400947580
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| 100 |
1 |
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|a Viehe, Heinz G.
|e [editor]
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| 245 |
0 |
0 |
|a Substituent Effects in Radical Chemistry
|h Elektronische Ressource
|c edited by Heinz G. Viehe, Zdenek Janousek, Robert Merényi
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| 250 |
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|a 1st ed. 1986
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| 260 |
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|a Dordrecht
|b Springer Netherlands
|c 1986, 1986
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| 300 |
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|a XIV, 482 p
|b online resource
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| 505 |
0 |
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|a 22. ESR-Spectroscopical Investigation of Carbohydrate Radicals in Solution. Radical Stabilization by Beta C-0 Bonds -- 23. Studies on the Captodative’ Effect. Entropy/Enthalpy Compensation as Solvent Effect in Radical Forming Reactions. A relative Radical Stabilisation Scale -- 24. ?° Revisited -- 25. Captodative Effect on the relative Rates of H-Abstraction by Tert-Butoxy Radicals -- 26. Substituent Effects in Gas-Phase Thermal Hydroxylation and Hydrogenolysis -- 27. Heterocyclic Substituents in SRNl Reactions -- 28. Substituent Effects on the Oxidation of Toluenes by Molecular Oxygen: The Surprising Reactivity of p-Methoxytoluene -- 29. Free Radical Additions of Dichloromethahe to ?-Alkenyl t-Butyl Peroxides -- 30. The Non-Chain Radicaloid Mechanism of Some Nucleophilic Substitution Reactions -- 31. Captodative Substituent Effects in Cycloaddition Reactions -- 32. Captodative Substitution Effect in [2+2] Cycloadditions Between Alienes and Olefins --
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| 505 |
0 |
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|a 33. Captodative Alkenes as Dipolarophiles—Kinetic Studies -- 34. Captodative Alkenes in Concerted 1, 3-Dipolar Cycloadditions -- 35. Photo-Diels-Alder Addition of Two Captodative Alkenes to 1-Acetonaphtone -- 36. Free Radical Cyclization of Unsaturated Carbonic acid Derivatives -- 37. Synthetic Applications of the Polar Effects of the Substituents in Free-Radical Reactions -- 38. Selectivity in Homolytic Aromatic Substitutions. Alkylations of Pyridines -- 39. The Invention of High-Yielding Radical Chain Reactions -- 40. Epilogue -- Participants
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| 505 |
0 |
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|a 1. A Theoretical Approach to Substituent Effects in radical Chemistry -- 2. Sigma and Pi Effects in Radicals -- 3. The Contrasting Strain Energies of Small Ring Carbon and Silicon Rings. The Relationship with Free Radical Energies -- 4. Allylic and Allenic Capto-dative Stabilization in Nitrogen Centered Free Radicals -- 5. Conformational Preferences in Beta Substituted Ethyl Radicals A Quantitative Analysis of Hyperconjugation, Homoconjugation, d-Orbital and Steric Effects -- 6. Substituent Effects on the Thermochemistry and Electrochemistry of Free Radicals -- 7. Some Applications of ES? Spectroscopy to the Study of Substituent Effects -- 8. Substituent Effects on Absolute Rate Constants and Arrhenius Parameters for the Addition of tert-Butyl Radicals to Alkenes -- 9. Allylic Radicals—An ESR Spectroscopical Study -- 10. ESR-Spectroscopical Investigation of Capto-dative Substituent Effects in Benzyl Radicals --
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| 505 |
0 |
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|a 11. The Effect of Substituents on Benzylic Radical ESR Hyperfine Coupling Constants. The ?? Scale Based Upon Spin Delocalization -- 12. Determination of Thermodynamic Stabilisation in Amino-Substituted Alkyl radicals -- 13. Phosphinylhydrazyls R2 NNP(O)L2. Influence of the Phosphinyl Group on the 3-Electron NN Pi Bond -- 14. Substituent Effects on the Dimerization of Vinyl Nitroxides and on the Dissociation of Their Tricyclic Dimers -- 15. Substituent Effects on the CC-Bond Strength -- 16. The Different Recombinations of Diphenyl Methyl Radicals Ph2 C°-R, R = tBu, CN, COOR’, COR’ -- 17. Some Chemistry of Radical Ions -- 18. Substituent Effects on the Methylenecyclopropane Rearrangement. A Probe for Free Radical Effects -- 19. 2-Oxomorpholin-3-yl Radicals -- 20. Azoalkane Decompositions as Measures of Radical Substituent Effects -- 21. Orbital Effects in CarbohydrateRadicals --
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| 653 |
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|a Chemistry, Organic
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| 653 |
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|a Organic Chemistry
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| 700 |
1 |
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|a Janousek, Zdenek
|e [editor]
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| 700 |
1 |
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|a Merényi, Robert
|e [editor]
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| 041 |
0 |
7 |
|a eng
|2 ISO 639-2
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| 989 |
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|b SBA
|a Springer Book Archives -2004
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| 490 |
0 |
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|a Nato Science Series C:, Mathematical and Physical Sciences
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| 028 |
5 |
0 |
|a 10.1007/978-94-009-4758-0
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| 856 |
4 |
0 |
|u https://doi.org/10.1007/978-94-009-4758-0?nosfx=y
|x Verlag
|3 Volltext
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| 082 |
0 |
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|a 547
|