Electron Spin Resonance Elementary Theory and Practical Applications
In the twenty-five years since its discovery by Zavoiskii, the technique of electron spin resonance (ESR) spectroscopy has provided detailed struc tural information on a variety of paramagnetic organic and inorganic sys tems. It is doubtful that even much later than 1945 any chemist would have bee...
| Main Authors: | , |
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| Format: | eBook |
| Language: | English |
| Published: |
Dordrecht
Springer Netherlands
1986, 1986
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| Subjects: | |
| Online Access: | |
| Collection: | Springer Book Archives -2004 - Collection details see MPG.ReNa |
Table of Contents:
- C-5 The Transition Frequencies in Constant Magnetic Field with a Varying Microwave Frequency
- C-6 The Resonant Magnetic Fields at Constant Microwave Frequency
- C-7 Calculation of the Energy Levels of the Hydrogen Atom by Perturbation Theory
- C-8 Wave Functions and Allowed Transitions for the Hydrogen Atom at Low Magnetic Fields
- Problems
- Appendix D. Experimental Methods; Spectrometer Performance
- D-1 Sensitivity
- D-2 Factors Affecting Sensitivity and Resolution
- D-2a Modulation Amplitude
- D-2b Modulation Frequency
- D-2c Microwave Power Level
- D-2d The Concentration of Paramagnetic Centers
- D-2e Temperature
- D-2g Microwave Frequency
- D-2h Signal Averaging
- D-3 Absolute Intensity Measurements
- Problems
- Table of Symbols
- Name Index
- Scalar, Vector, and Outer Products
- A-5 Matrices
- A-5a Addition and Subtraction of Matrices
- A-5b Multiplication of Matrices
- A-5c Special Matrices and Matrix Properties
- A-5d Dirac Notation for Wave Functions and Matrix Elements
- A-5e Diagonalization of Matrices
- A-6 Tensors
- A-7 Perturbation Theory
- A-8 Euler Angles
- Problems
- Appendix B. Quantum Mechanics of Angular Momentum
- B-1 Introduction
- B-2 Angular-momentum Operators
- B-3 The Commutation Relations for the Angular-momentum Operators
- B-6 Angular-momentum Matrices
- B-7 Addition of Angular Momenta
- B-8 Summary
- Problems
- C-1 The Hamiltonian for the Hydrogen Atom
- C-2 The Spin Eigenfunctions and the Energy Matrix for the Hydrogen Atom
- C-3 Exact Solution of the Determinant of the Energy Matrix (Secular Determinant)
- C-4 Selection Rules for High-field Magnetic-dipole Transitions in the Hydrogen Atom
- 1 Basic Principles of Electron Spin Resonance
- 2 Basic Instrumentation of Electron Spin Resonance
- 3 Nuclear Hyperfine Interaction
- 4 Analysis of Electron Spin Resonance Spectra of Systems in the Liquid Phase
- 5 Interpretation of Hyperfine Splittings in ?-type Organic Radicals
- 6 Mechanism of Hyperfine Splittings in Conjugated Systems
- 7 Anisotropic Interactions in Oriented Systems with S = 1/2
- 8 Interpretation of the ESR Spectra of Systems in the Solid State
- 9 Time-dependent Phenomena
- 10 Energy-level Splitting in Zero Magnetic Field; The Triplet State
- 11 Transition-metal Ions. I.
- 12 Transition-metal Ions. II. Electron Resonance in the Gas Phase
- 13. Double-resonance Techniques
- 14. Biological Applications of Electron Spin Resonance
- Appendix A. Mathematical Operations
- A-1 Complex Numbers
- A-2 Operator Algebra
- A-2a Properties of Operators
- A-2b Eigenvalues and Eigenfunctions
- A-3 Determinants