Free Radicals in Synthesis and Biology
Free-radical reactions have been for long time the domain of the physical chemists and the basic chemical industry (polymerization of vinyl monomers, oxidation by molecular oxygen, chlorination of methane etc.), where the use of simple molecules and the possibility of partial conversions without hea...
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| Format: | eBook |
| Language: | English |
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Dordrecht
Springer Netherlands
1989, 1989
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| Edition: | 1st ed. 1989 |
| Series: | Nato Science Series C:, Mathematical and Physical Sciences
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| Subjects: | |
| Online Access: | |
| Collection: | Springer Book Archives -2004 - Collection details see MPG.ReNa |
Table of Contents:
- 34. The Chemistry/Biochemistry Interface in Free Radical Reactions
- 23. Polar Effects on Radical Addition Reactions: An Ambiphilic Radical
- 24. The Effect of Temperature in the Reactions of Arenesulphonyl Radicals
- 25. Synthesis of New 5-Nitroimidazoles Highly Active against Anaerobes by Substitution Reactions which Proceed via Radical and Radical-Anion Intermediates
- 26. Electron Spin Resonance Studies of the Reactions of •OH and SO4•- Radicals with DNA, Polynucleotides and Single Base Model Compounds
- 27. Detection of Free Radicals in Biochemistry by Electron Spin Resonance Spectroscopy
- 28. Error in Enzymic Stereospecificity as a Probe for the Occurence of Radical Intermediates
- 29. Kinetics of Peroxyl Radical Reactions in Model Biomembranes
- 30. Rearrangements of Optically Pure Hydroperoxides
- 31. In vivo Detection of Free Radical Metabolites
- 32. The Involvement of Free Radicals in the Metabolism of Drugs
- 33. The Formation of Fluorescent Pigments Due to Radicals in Biological Tissues
- 1. Captodative Substituent Effects in Synthesis
- 2. The Influence of gem-Substitution on the CC-Bond
- 3. Iodine Atom Transfer Reactions in Organic Synthesis
- 4. Alkyl Iodides as Source of Alkyl Radicals, Useful for Selective Syntheses
- 5. Introduction of a Single Electron-with-drawing Carbon Substituent into ? -Deficient N-Heteroarenes by Means of Free-Radical Reactions: Strategies and Synthetic Applications
- 6. Free Radical Syntheses of Pyridylderivatives: Influence of the Solvent
- 7. Photoinitiated Radical Reactions of 1-(4?-Pyridyl)-4-Pyridane and Its N-Protio and N-Methyl derivatives. Dimerization and Polymerization Reactions
- 8. Radical Reactions with Organocobalt Complexes
- 9. New Ways of Generating Stannyl Radicals for Organic Syntheses
- 10. Silanes as New Reducing Agents in Organic Synthesis
- 11. Acyl, Imidoyl and Other Hetero-substituted Free Radicals as Intermediates in the Synthesis of Cyclic Organic Compounds
- 12. Some Studies on Carbonyl Radical Cyclizations on the Synthesis of 2-Deoxy-?-D-glycosides by Stereoselective Radical Reactions
- 13. Stereoselective Formation of Linear Aza-Triquinanes by Three Consecutive Radical Ring Closures
- 14. Synthetic Applications of Substitution and Addition Reactions Promoted by Cerium (IV) Ammonium Nitrate
- 15. Use of Homolytic Redox Processes in Organic Syntheses
- 16. One-Electron Redox Reactions between Radicals and Molecules. Dominance of Inner-Sphere Mechanisms
- 17. Electron-Transfer Photosensitization in the Oxidation of Alkyl Aromatics and Heteroaromatics
- 18. Selenium Radical Ions in Organic Synthesis
- 19. A. Synthetically Useful Source of Alkyl and Acyl Radicals
- 20. Chlorination of Hypochlorous Acid. Free-Radical versus Electrophilic Reactions
- 21. Induced Decomposition of Peroxycompoundsin Synthesis: Free Radical Functionalization of Crown Ethers
- 22. Unwanted Synthesis in Combustion and Pyrolysis: Soot and Dioxins