Unified Valence Bond Theory of Electronic Structure
| Main Author: | |
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| Format: | eBook |
| Language: | English |
| Published: |
Berlin, Heidelberg
Springer Berlin Heidelberg
1982, 1982
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| Edition: | 1st ed. 1982 |
| Series: | Lecture Notes in Chemistry
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| Subjects: | |
| Online Access: | |
| Collection: | Springer Book Archives -2004 - Collection details see MPG.ReNa |
Table of Contents:
- I Qualitative Valence Bond Theory of Model Systems
- A. The Formal and Conceptual Difficulties of MO Theory
- B. Levels of VB and MO Theories
- C. Qualitative Valence Bond Theory
- D. Physical Interpretation of Diagonal Energy Matrix Elements
- E. Physical Interpretation of the Interactions of CW’s: “Ionic” versus “Covalent” Delocalization
- F. Diagrammatic Matrix Elements
- G. The VB Theory of Aromaticity
- H. Heitier - London Theory of Stereoselection
- I. The “Perfect” Form of Heitler - London Theory
- J. Why HL Theory Cannot Qualify as a General Theory of Chemical Bonding
- K. The Transition to “Orthogonal” VB Theory and Its Approximate Variants
- L. The Physical Interpretation of VB Configuration Wavefunctions.
- M. Huckel Valence Bond Theory of Stereoselection
- N. Neglect of Differential Overlap Valence Bond Theory of Stereoselection
- O. The Electronic Basis of Stereoselection
- P. Conclusion
- References
- Appendices
- II Qualitative Molecular Orbital-Valence Bond Theory
- A. MOVB Theory
- B. The MOVB Approach to Ground State Stereochemistry
- C. Ground State Bond Diagrams
- D. The Representation of Elementary Systems
- E. The Basic Stereochemical Problems
- F. Selection Rules for Chemical Bonding
- G. The Concept of the Effective Energy Gap
- H. The Representation of Polyelectronic Systems
- I. Core and Ligand Group Orbitals
- J. Applications
- K. Compact MOVB Theory
- L. Epilogue
- References