Inert Gases Potentials, Dynamics, and Energy Transfer in Doped Crystals
Research involving the chemical physics of the inert or rare gases continues unabated. This small volume is meant to deal with advances that have occurred in three selected areas over the past decade. It forms a natural outgrowth of earlier reviews and volumes that have dealt almost exclusively with...
| Other Authors: | |
|---|---|
| Format: | eBook |
| Language: | English |
| Published: |
Berlin, Heidelberg
Springer Berlin Heidelberg
1984, 1984
|
| Edition: | 1st ed. 1984 |
| Series: | Springer Series in Chemical Physics
|
| Subjects: | |
| Online Access: | |
| Collection: | Springer Book Archives -2004 - Collection details see MPG.ReNa |
Table of Contents:
- f) Krypton Doped with Xenon
- 3.4.2 Molecules in RGS
- a) Homonuclear Diatomics
- b) Heteronuclear Diatomics
- c) RGS Doped with Methane
- a) Molecular Ions
- b) Molecules
- c) Atoms
- 3.5 Summary
- References
- 4. Spectroscopy of Vibrational and Rotational Levels of Diatomic Molecules in Rare-Gas Crystals
- 4.1 Background
- 4.2 Experimental Techniques and Results
- a) Sample Preparation
- b) Spectroscopy (Conventional Versus Laser)
- c) Saturation Spectroscopy or Hole Burning
- d) Time-Resolved Spectroscopy
- a) Vibrational Transitions
- b) Rotational Transitions
- c) Phonon Sidebands
- a) Infrared Spectroscopy
- b) Visible Spectroscopy
- 4.3 Intermolecular Interaction in Rare-Gas Crystals Containing Molecular Defects
- a) Atom-Atom Potential
- b) Multiparameter Potential Functions
- c) Ab Initio Potential Surfaces
- d) ChargeTransfer and Hydrogen Bonding
- a) Energy Levels
- b) Relaxation Processes
- 4.4 Perturbation of Energy Levels
- 1. Argon and Its Companions.
- 1.1 Prologue: Inert, Rare or Noble?
- 1.2 Research with Inert Gases
- 1.3 Outline of the Present Book
- References
- 2. Interatomic Potentials for Rare-Gases: Pure and Mixed Interactions
- 2.1 Background
- 2.2 What Probes What?
- 2.3 Review of Recent Research on Pure Interactions
- 2.4 Review of Recent Research on Unlike Interactions
- 2.5 Combining Rules
- 2.6 Conclusions
- Appendix: 2.A Interatomic Potential Functions
- 2.B Interatomic Potential Parameters
- 2.C Predictions of Collisons Cross-Sections by Potentials
- References
- 3. Dynamics of Impure Rare-Gas Crystals
- 3.1 Background
- 3.2 Lattice Dynamics of Impure Crystals
- 3.3 Theoretical Studies
- a) Potentials
- b) Relaxation Effects
- c) Three-Body Forces
- d) Phonon Density of States
- 3.4 Experimental Studies
- a) Argon Doped with Krypton
- b) Argon Doped with Neon
- c) Argon Doped with Helium
- d) Argon Doped with Xenon
- e) Krypton Doped with Argon
- a) Effect of Isotropic Terms
- b) Effect of Internal Molecular Motions
- c) Description of Lattice Vibrations Through Molecular Dynamics
- d) Phonon Sidebands in IR Spectra of the Guest Molecule
- a) Vibrational Matrix Shift
- b) Rotational Matrix Shift
- 4.5 Population Relaxation Processes
- a) Microscopic Processes Among Molecules in Rare-Gas Crystals
- b) Microscopic Probabilities for Vibrational Energy Transfer
- c) Macroscopic Kinetics for Vibrational Energy Transfer
- d) Comparison Between Theory and Experiment
- a) The Direct Process
- b) Raman and Orbach Processes
- 4.6 Spectral Line Shapes and Dephasing Processes
- a) Isolated Vibrational Levels with a Large Spacing
- b) Additional Low-Energy Levels in the Molecule
- 4.7 Concluding Remarks
- References
- Additional References with Titles