Thermodynamic Data on Oxides and Silicates An Assessed Data Set Based on Thermochemistry and High Pressure Phase Equilibrium

Main Authors: Saxena, Surendra K., Chatterjee, Nilanjan (Author), Fei, Yingwei (Author), Shen, Guoyin (Author)
Corporate Author: SpringerLink (Online service)
Format: eBook
Published: Berlin, Heidelberg Springer Berlin Heidelberg 1993, 1993
Edition:1st ed. 1993
Online Access:
Collection: Springer Book Archives -2004 - Collection details see MPG.ReNa
Table of Contents:
  • Thermodynamic Data Systematics
  • 2. Thermodynamic Relations
  • Temperature and pressure dependence of the Gibbs free energy
  • Heat capacity at high temperature
  • Estimation of Cv
  • Method of optimization
  • Anderson’s enthalpy/bulk modulus relationship
  • Some comparisons
  • Molar volume at high pressure and high temperature
  • The use of the Birch-Murnaghan (BM) equation at high temperature
  • Comparison with Anderson’s model
  • 3. Techniques for Data Assessment
  • Computational techniques
  • The manual adjustment approach using free energy minimization
  • The regression technique
  • The optimization technique
  • Phase equilibrium calculation by SOLGASMIX
  • 4. Assessment of Data on Some Oxides and Silicates: Calorimetry and Low-pressure Phase Equilibrium Experiments
  • The system Si02
  • Andalusite, kyanite and sillimanite
  • Wollastonite, gehlenite, akermanite and monticellite
  • Enstatite and pyrope
  • Forsterite
  • Fayalite and ferrosilite
  • Tables of Thermodynamic Data
  • Appendix II: Summary of Reactions in the Mg-Fe-Si-O system
  • Species Index
  • Calorimetry and High-Pressure Phase Equilibrium Experiments
  • System Fe-0
  • Polymorphism of Fe
  • Wustite
  • Magnetite and hematite
  • System MgO-SiO2
  • Polymorphism of SiO2
  • Polymorphism of Mg2Si04
  • Polymorphism of MgSi03
  • System FeO-SiO2
  • Polymorphism of Fe2SiO4
  • Polymorphism of FeSiO3,
  • 6. Assessment of Solid Solution Parameters for Some Silicates
  • Solid solution models
  • Gehlenite-akermanite
  • Spinel-hercynite
  • Forsterite-fayalite
  • Forsterite-monticellite