Chromium Oxidations in Organic Chemistry
Chromium oxidation, well known and widely explored in organic chemistry since the very beginning of this science, is a topic of current interest for the organic chemist as evidenced by the continuous development of new techni ques and procedures reported in the literature. Chromium oxidation is a s...
| Main Authors: | , |
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| Format: | eBook |
| Language: | English |
| Published: |
Berlin, Heidelberg
Springer Berlin Heidelberg
1984, 1984
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| Edition: | 1st ed. 1984 |
| Series: | Reactivity and Structure: Concepts in Organic Chemistry
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| Subjects: | |
| Online Access: | |
| Collection: | Springer Book Archives -2004 - Collection details see MPG.ReNa |
Table of Contents:
- 4. Oxidation of Hydroquinone Silyl Ethers With Pyridinium Chlorochromate
- 5. Oxidation of Ortho-Allylphenols With Tetraalkylammonium Dichrornate
- 6. Oxidation of Some Aromatic Heterocyclic Compounds With Chromium(VI)
- References of Chapter III
- IV. Oxidation of Alcohols
- A. Oxidation of Alcohols by Chromium(VI) Under Acidic Conditions
- B. Oxidation of Alcohols With Compounds of Chromium(VI) and Heterocyclic Bases
- C. Oxidation of Alcohols With Chromium(VI) Under Neutral Conditions
- D. Oxidation of Alcohols With Supported Chromium(VI) Reagents
- E. Mechanism of Oxidation of Alcohols
- F. Effect of the Structure and Stereochemistry of Secondary Alcohols on the Rate of Oxidation
- References of Chapter IV
- V. Oxidation of Aldehydes and Ketones
- A. Oxidation of Aldehydes
- B. Oxidation of Ketones
- References of Chapter V
- VI. Oxidation of Carbon-Metal Bonds
- A. Oxidation of Organoboron Compounds
- B. Oxidation of Organotin Compounds
- I. Introduction
- 1. The Oxidation States of Chromium
- 2. The Chemistry of Chromium(VI)
- 3. Chromium(VI) as Oxidant in Organic Chemistry
- References of Chapter I
- II. Oxidation of Carbon-Hydrogen Bonds
- A. Oxidation of Alkanes
- B. Oxidation of Arylalkanes (Benzylie Oxidation)
- C. Allylic Oxidation
- 1. Allylic Oxidation of Olefins With Chromium(VI) in Acetic Acid and Acetic Anhydride
- 2. Allylic Oxidation With Chromium Trioxide-Heterocyclic Bases Addition Compounds
- 3. Allylic Oxidation With Tert-butyl-chrornate
- 4. Mechanism of Allylic Oxidation
- References of Chapter II
- III. Oxidation of Carbon-Carbon Double Bonds
- A. Oxidation of Alkenes
- C. Ring Oxidation of Aromatic Compounds
- 1. Oxidation of Polynuclear Arenes With Chromium(VI) Under Acidic Conditions
- 2. Oxidation of Phenols and Aromatic Amines With Chromium(VI) Under Acidic Conditions
- 3. Oxidation of Phenols With Chromyl Chloride
- References of Chapter VI
- VII. Oxidation of Halides, Ethers, Acetals, Sulphides, and Some Nitrogen Containing Compounds
- A. Oxidation of Alkyl Halides
- B. Oxidation of Ethers
- C. Oxidation of Acetals
- D. Oxidation of Sulphides
- E. Oxidation of Alkyl Aryl Amines
- F. Oxidation of Oximes
- G. Oxidation of Hydroxylamine
- References of Chapter VII
- VIII. Some Remarks on Selectivity and Synthetic Use of Chromium (VI) Oxidation
- A. Oxidation of Carbon-Hydrogen Bond
- B. Oxidation of Carbon-Carbon Double Bonds
- C. Ring Oxidation of Aromatic Compounds
- D. Oxidation of Alcohols
- E. Oxidation of Aldehydes and Ketones
- F. Oxidation of Carbon-Metal Bonds