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140122 ||| eng |
| 020 |
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|a 9783642686764
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| 100 |
1 |
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|a Kirby, A. J.
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| 245 |
0 |
0 |
|a The Anomeric Effect and Related Stereoelectronic Effects at Oxygen
|h Elektronische Ressource
|c by A. J. Kirby
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| 250 |
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|a 1st ed. 1983
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| 260 |
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|a Berlin, Heidelberg
|b Springer Berlin Heidelberg
|c 1983, 1983
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| 300 |
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|a VIII, 152 p
|b online resource
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| 505 |
0 |
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|a A. Stereoelectronic Effects on Structure -- 1. Introduction -- 2. The Anomeric Effect -- 3. The Reverse Anomeric Effect -- 4. The Exo-Anomeric Effect -- 5. The Generalised Anomeric Effect -- 6. The Gauche Effect -- B. The Electronic Basis of the Effects -- 1. Introduction -- 2. The Status of Lone Pair Electrons -- 3. Calculations on X?Y Systems -- 4. Effects on Bond Lengths and Angles -- 5. Effects in Furanoses -- 6. The Stereoelectronic Basis of the Anomeric Effect -- 7. Related Stereoelectronic Effects -- C. Stereoelectronic Effects on Reactivity: The Kinetic Anomeric Effect -- 1. Introduction -- 2. Reactions of the Acetal Group -- 3. The Hydrolysis of Orthoesters -- 4. Carbonyl-Oxygen Exchange Reactions of Esters and Amides -- 5. The Hydrolysis of Imidate Esters: Stereoelectronic Effects at Oxygen and Nitrogen -- 6. Reactions of Phosphate Esters -- 7. Radical Reactions -- 8. Enzyme Reactions -- D. Appendix -- 1. Canonical Lone Pair Description -- 2. Hybrid Lone Pair Description -- E. References -- F. Subject Index
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| 653 |
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|a Chemistry, Organic
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| 653 |
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|a Organic Chemistry
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| 041 |
0 |
7 |
|a eng
|2 ISO 639-2
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| 989 |
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|b SBA
|a Springer Book Archives -2004
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| 490 |
0 |
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|a Reactivity and Structure: Concepts in Organic Chemistry
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| 028 |
5 |
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|a 10.1007/978-3-642-68676-4
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| 856 |
4 |
0 |
|u https://doi.org/10.1007/978-3-642-68676-4?nosfx=y
|x Verlag
|3 Volltext
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| 082 |
0 |
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|a 547
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