Cyclodextrin Chemistry
Chemistry was at one time completely described in terms of collision theo ry, in which one molecule collided with another, sometimes producing reac tion. Then came the realization that enzymes which are highly efficient ca talysts, work by way of prior complexation, often stereospecific, which is...
| Main Authors: | , |
|---|---|
| Format: | eBook |
| Language: | English |
| Published: |
Berlin, Heidelberg
Springer Berlin Heidelberg
1978, 1978
|
| Edition: | 1st ed. 1978 |
| Series: | Reactivity and Structure: Concepts in Organic Chemistry
|
| Subjects: | |
| Online Access: | |
| Collection: | Springer Book Archives -2004 - Collection details see MPG.ReNa |
Table of Contents:
- I. Introduction
- II. Properties
- 1. Source and Nomenclature
- 2. Structure and Physical Properties
- III. Inclusion Complex Formation
- 1. Detection of Complex Formation and Structure of the Complexes
- 2. The Determination of Dissociation Constants of Inclusion Complexes
- 3. Binding Force of the Complexes
- IV. Catalyses by Cyclodextrins Leading to Practical Usages of Cyclodextrins
- V. Covalent Catalyses
- 1. Hydrolyses of Phenyl Esters
- 2. Hydrolyses of Amides
- 3. Hydrolyses of Organophosphates and Carbonates
- VI. Noncovalent Catalyses
- 1. The Microsolvent Effect
- 2. The Conformational Effect
- VII. Asymmetric Catalyses by Cyclodextrins
- 1. Selective Precipitation of d, l Compounds
- 2. Hydrolyses of Esters
- 3. Cleavage of Organophosphates
- 4. Addition and Oxidation Reactions
- VIII. Improvement by Covalent and Noncovalent Modification
- 1. Acceleration of the Deacylation Step
- 2. Better Models of Hydrolytic Enzymes
- 3. Cyclodextrins Containing Metal Ions
- IX. Conclusion
- References
- Author Index