31P and 13C NMR of Transition Metal Phosphine Complexes
For almost a quarter of a century the words "nuclear magnetic reso nance" were synonymous with proton I,leasurements. During this period the literature abounded with a seemingly infinite variety of 1H NHR studies concerned primarily with carbon chemistry. Occasionally a "novel"...
| Main Authors: | , |
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| Format: | eBook |
| Language: | English |
| Published: |
Berlin, Heidelberg
Springer Berlin Heidelberg
1979, 1979
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| Edition: | 1st ed. 1979 |
| Series: | NMR Basic Principles and Progress
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| Subjects: | |
| Online Access: | |
| Collection: | Springer Book Archives -2004 - Collection details see MPG.ReNa |
Table of Contents:
- A Motivation and Methodology
- I Introduction
- II Measurement Techniques
- III Spin-Lattice Relaxation Times
- IV The 31P Nuclear Overhauser Effect
- B Coupling Constants
- I One-Bond Metal-Phosphorus Coupling Constants
- II Two-Bond Phosphorus-Phosphorus Coupling Constants
- III One-Bond Metal-Phosphorus Coupling Constants — A Survey
- IV Two-Bond Phosphorus-Phosphorus Coupling Constants — Data
- C Chemical Shifts
- D Applications
- E 13C Studies of Phosphorus Containing Complexes
- I Studies of Coordinated Phosphorus Ligands
- II Studies of Non-Phosphorus Ligands in Phosphorus-Complexes
- F Appendices
- A The Influence of Tr-Orbitals on the Coupling Constant
- B Numerical Values of /?ns(O)/2
- C Differences in 1J(M,P), 2J(P,P)cis and 2J(P,P)trans
- G Tables
- H References