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Transport, Relaxation, and Kinetic Processes in Electrolyte Solutions

The presence of freely moving charges gives peculiar properties to electrolyte solutions, such as electric conductance, charge transfer, and junction potentials in electrochemical systems. These charges play a dominant role in transport processes, by contrast with classical equilibrium thermodynamic...

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Bibliographic Details
Main Authors: Turq, Pierre, Barthel, Josef M.G. (Author), Chemla, Marius (Author)
Format: eBook
Language:English
Published: Berlin, Heidelberg Springer Berlin Heidelberg 1992, 1992
Edition:1st ed. 1992
Series:Lecture Notes in Chemistry
Subjects:
Chemistry, Physical And Theoretical
Physical Chemistry
Theoretical Chemistry
Online Access:
Collection: Springer Book Archives -2004 - Collection details see MPG.ReNa
Table of Contents:
  • I: Basic Concepts
  • 1.1 Introduction
  • 1.2 Systems in Thermodynamic Equilibrium
  • 1.3 Electrolyte Solutions
  • 1.4 Preliminary Remarks on Transport Processes
  • II: Coupled Processes and Chemical Reactions in Solutions
  • 2.1 Continuity Equations
  • 2.2 Mass Conservation
  • 2.3 Constitutive Equations
  • 2.4 Solutions of the Basic Transport Equations
  • 2.5 Normal Modes
  • 2.6 Coupled Diffusion
  • III: Hydrodynamic Properties
  • 3.1 Introduction
  • 3.2 General Aspects of Hydrodynamics
  • 3.3 Inviscid Fluids
  • 3.4 Viscous Incompressible Fluids
  • 3.5 Stokes Approximation
  • 3.6 Hydrodynamic Interactions of Moving Spheres
  • IV: Excess Quantities
  • 4.1 Distribution and Correlation Functions
  • 4.2 Debye-Hückel Limiting Law
  • 4.3 Activity Coefficients
  • 4.4 Chemical Model
  • 4.5 Electrolyte Solutions at Moderate to High Concentrations
  • 4.6 Hydrodynamic Interactions
  • V: The Role of Ion Aggregation and Micelle Formation Kinetics in Diffusional Transport of Binary Solutions
  • 5.1 Diffusional Transport of Symmetrical Electrolytes
  • 5.2 Some Remarks on the Diffusional Transport of Symmetrical Electrolytes
  • 5.3 Diffusional Transport of Unsymmetrical Electrolytes
  • 5.4 Monomer-Micelle Exchange in Micelle Diffusion
  • 5.5 Concluding Remarks
  • VI: Diffusion, Migration and Chemical Reactions in Electrolyte Solutions beyond Ideality
  • 6.1 Introduction
  • 6.2 Electrolyte Conductance
  • 6.3 Apparent Ionic Charge
  • 6.4 Experimental Contributions to the Apparent Charge Concept
  • 6.5 Solutions of Complex Electrolytes
  • 6.6 Electrophoretic Transport and Exchange Reactions
  • VII: Relaxation. Processes in High Frequency Electromagnetic Fields
  • 7.1 Fundamental Equations
  • 7.2 Electric Polarization
  • 7.3 Response Functions and Relaxation Times
  • 7.4 Relaxation Processes in Solvents and Their ElectrolyteSolutions

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