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140122 ||| eng |
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|a 9783540494515
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|a Meijere, Armin de
|e [editor]
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245 |
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|a Carbon Rich Compounds II
|h Elektronische Ressource
|b Macrocyclic Oligoacetylenes and Other Linearly Conjugated Systems
|c edited by Armin de Meijere
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250 |
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|a 1st ed. 1999
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260 |
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|a Berlin, Heidelberg
|b Springer Berlin Heidelberg
|c 1999, 1999
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300 |
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|a XI, 227 p. 4 illus
|b online resource
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|a Macrocyclic Structurally Homoconjugated Oligoacetylenes: Acetylene- and Diacetylene-Expanded Cycloalkanes and Rotanes -- Cyclic and Linear Acetylenic Molecular Scaffolding -- Macrocyclic Oligo(phenylacetylenes) and Oligo(phenyldiacetylenes) -- Carbon-Rich Molecular Objects from Multiply Ethynylated ?-Complexes -- Oligo- and Polyarylenes, Oligo- and Polyarylenevinylenes
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653 |
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|a Chemistry, Organic
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653 |
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|a Organic Chemistry
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7 |
|a eng
|2 ISO 639-2
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989 |
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|b SBA
|a Springer Book Archives -2004
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490 |
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|a Topics in Current Chemistry
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|a 10.1007/3-540-49451-0
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|u https://doi.org/10.1007/3-540-49451-0?nosfx=y
|x Verlag
|3 Volltext
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|a 547
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|a The definition of Carbon Rich Compounds applied in this as in the previous volume (TCC Volume 196) of this series on the same general topic comprises carbon skeletons with a carbon to hydrogen ratio of 1:(kleiner gleich 1), which ultimately implies all-carbon compounds (i.e. carbon allotropes). The current volume covers modern methods for the coupling - mostly metal catalyzed - of subsystems consisting of double bonds, cyclopropyl groups, arenes, and metal-complexed pi-systems with acetylene and diacetylene units. The resulting structures range from macrocycles, including those with all sorts of linkers between the acetylene and diacetylene units, to conducting polymers and light-emitting materials. Wherever appropriate, chemical transformations of these intriguing compounds and materials are discussed as well
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