Transition Metal Arene π-Complexes in Organic Synthesis and Catalysis

Metal-arene p-complexes show a rich and varied chemistry. The metal adds a third dimension to the planar aromatic compounds and coordination of a metal to an arene thus not only altering the reactivity of ring-carbons and substituents but also makes possible reactions that lead to chiral non-racemic...

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Bibliographic Details
Other Authors: Kündig, Peter E. (Editor)
Format: eBook
Language:English
Published: Berlin, Heidelberg Springer Berlin Heidelberg 2004, 2004
Edition:1st ed. 2004
Series:Topics in Organometallic Chemistry
Subjects:
Online Access:
Collection: Springer Book Archives -2004 - Collection details see MPG.ReNa
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100 1 |a Kündig, Peter E.  |e [editor] 
245 0 0 |a Transition Metal Arene π-Complexes in Organic Synthesis and Catalysis  |h Elektronische Ressource  |c edited by Peter E. Kündig 
250 |a 1st ed. 2004 
260 |a Berlin, Heidelberg  |b Springer Berlin Heidelberg  |c 2004, 2004 
300 |a VIII, 232 p  |b online resource 
505 0 |a E.P. Kündig: Introduction -- E.P. Kündig: Synthesis of Transition Metal h6-Arene Complexes -- M.F. Semmelhack, A. Chlenov: (Arene)Cr(CO)3 Complexes: Arene Lithiation/Reaction with Electrophiles -- M.F. Semmelhack, A. Chlenov: (Arene)Cr(CO)3 Complexes: Aromatic Nucleophilic Substitution -- E.P. Kündig, A. Pape: Dearomatization via h6-Arene Complexes -- W.D. Harman: The Dearomatization of Arenes by Dihapto-Coordination -- M. Uemura: (Arene)Cr(CO)3 Complexes: Cyclization-, Cycloaddition- and Cross Coupling Reactions -- H.-G. Schmalz, B. Gotov and A. Böttcher: Natural Product Synthesis -- J.H. Rigby, M.A. Kondratenkov: Arene Complexes as Catalysts -- K. Muñiz: Planar Chiral Arene Chromium (0) Complexes as Ligands for Asymmetric Catalysis 
653 |a Inorganic chemistry 
653 |a Medicinal chemistry 
653 |a Condensed Matter Physics 
653 |a Organometallic Chemistry 
653 |a Organometallic chemistry  
653 |a Inorganic Chemistry 
653 |a Medicinal Chemistry 
653 |a Condensed matter 
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520 |a Metal-arene p-complexes show a rich and varied chemistry. The metal adds a third dimension to the planar aromatic compounds and coordination of a metal to an arene thus not only altering the reactivity of ring-carbons and substituents but also makes possible reactions that lead to chiral non-racemic products. This book, organized in nine chapters and written by leading scientists in the field provides the reader with an up-to-date treatise on the subject organized according to reaction type and use. It covers the wide spectrum of arene activation: from the electrophilic activation of h6-bound areneï⿬ by p-Lewis acid metal complex fragments, to reactions of nucleophilic h2-coordinated arene complexes. The preparation of complexes is detailed, as are the scope, limitations and challenges of reactions in contemporary p-arene metal chemistry with special attention given to asymmetric transformations. The emphasis of the book is on transformations of interest to organic synthesis and on the use of the complexes as catalysts or as chiral ligands. The book is written for academic and industrial researchers in organic, organometallic, and inorganic chemistry as well as for advanced chemistry students