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Ion-Exchange Sorption and Preparative Chromatography of Biologically Active Molecules

This book deals with the physico-chemical principles underlying ion­ exchange sorption and chromatog~aphy. It does not cover in any detail the experimental and instrumental aspects of practical separations. The author has developed the subject starting from the synthesis and structure of the ion exc...

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Bibliographic Details
Main Author: Samsonov, G.V.
Format: eBook
Language:English
Published: New York, NY Springer US 1986, 1986
Edition:1st ed. 1986
Series:Macromolecular Compounds
Subjects:
Physical Chemistry
Analytical Chemistry
Online Access:
Collection: Springer Book Archives -2004 - Collection details see MPG.ReNa
Table of Contents:
  • One Introduction
  • 1.1 The Problems of Fine Physico-Chemical Biotechnology
  • 1.2 Physico-Chemical Methods of Separating Mixtures
  • 1.3 Preparative Selective Sorption and Chromatography
  • Two Ionite Permeability and Porosity
  • 2.1 Types of Highly Permeable Network Polyelectrolytes
  • 2.2 Methods for Studying the Permeability and Porosity of Network Polyelectrolytes
  • 2.3 The Structure and Properties of Very Permeable Network Polyelectrolytes
  • 2.4 The Conformational State and Flexibility of the Structural Elements of Network Polyelectrolytes
  • Three Ion-Exchange Equilibrium, Thermodynamics, and Sorption Selectivity of Organic and Physiologically Active Substances
  • 3.1 Ionite Exchange Capacity
  • 3.2 Equivalence of Ion Exchange
  • 3.3 Ion-Exchange Processes without the Sorption of Physiologically Active Substances
  • 3.4 Isotherms of Equivalent Ion Exchange
  • 3.5 Ion Exchange on Ionites with Heterogeneous Active Centers
  • 3.6 The Selectivity of Ion Exchange as a Function of the Counter-Ion Mole Fraction in the Ionite
  • 3.7 Sorption Selectivity of Ions as a Function of Electrolyte Concentration in the External Solution
  • 3.8 Ion Exchange with Weak Electrolytes
  • 3.9 Ion Exchange, Hydration, and Swelling
  • 3.10 Selective Sorption of Organic Ions
  • 3.11 Sorption of Organic Ions and Ionite Particle Size
  • 3.12 Ion Exchange with Physiologically Active Substances
  • Four Equilibrium Dynamics of Ion Sorption and Standard Quasi-Equilibrium Frontal Chromatography
  • 4.1 Sharp Front Formation for the Exchange of Ions with the Same Valence
  • 4.2 Formation of Sharp Fronts during the Exchange of Ions with Different Valences
  • 4.3 Formation of Sharp Fronts when Two Liquids Are Involved
  • 4.4 Sorption-Displacement for a Multicomponent Exchange in a Column
  • 4.5 Standard Quasi-Equilibrium Frontal Chromatography on Ionites
  • Five Kinetics and Non-Equilibrium Ion-Exchange Dynamics
  • 5.1 The Diffusion of Organic Ions in Ionites
  • 5.2 Theoretical Problems of Non-Equilibrium Dynamics of Sorption and Chromatography Involving Slowly Diffusing Organic Ions in Ionite Grains
  • 5.3 Increasing the Efficiency of Low-Pressure Chromatography by Using Surface-Layer and Bidispersed Ionites
  • References

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