The Physics and Physical Chemistry of Water
to arrive at some temporary consensus model or models; and to present reliable physical data pertaining to water under a range of conditions, i.e., "Dorsey revisited," albeit on a less ambitious scale. I should like to acknowledge a debt of gratitude to several of my col leagues, to Prof....
Other Authors: | |
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Format: | eBook |
Language: | English |
Published: |
New York, NY
Springer US
1972, 1972
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Edition: | 1st ed. 1972 |
Series: | Water, a comprehensive treatise
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Subjects: | |
Online Access: | |
Collection: | Springer Book Archives -2004 - Collection details see MPG.ReNa |
Table of Contents:
- 6. Water Polymers
- 7. Spectroscopic Properties, Proton Potential Functions, Charge Distribution, and Related Aspects
- 8. Conclusions
- 4 The Properties of Ice
- 1. Introduction
- 2. Phase Behavior of Ice
- 3. Structures of Crystalline Ice Phases
- 4. Thermodynamic Properties of Ice Polymorphs
- 5. Mechanical Properties
- 6. Lattice Dynamics
- 7. Molecular and Ionic Transport in Ice
- 8. Summary
- 5 Raman and Infrared Spectral Investigations of Water Structure
- 1. Introduction
- 2. New Experimental Techniques
- 3. Intermodular Vibrations of H2O and D2O
- 4. Intramolecular Vibrational Spectra from H2O in H2O and D2O
- 5. Intramolecular Vibrational Spectra from H2O and D2O
- 6. Relation of Component Properties to Water Structure
- 7. Thermodynamic Tests of the Consecutive Hydrogen-Bond Disruption Model
- 8. Currentand Future Work
- 6 Nuclear Magnetic Resonance Studies on Water and Ice
- 1. Theoretical and Experimental Foundations of Magnetic Resonance
- 1 Introduction—Water, the Unique Chemical
- 1. Introduction
- 2. The Occurrence and Distribution of Water on the Earth
- 3. Water and Life
- 4. The Scientific Study of Water—A Short History
- 5. The Place of Water among Liquids
- 2 The Water Molecule
- 1. Introduction
- 2. Principles of Structure and Spectra: The Born-Oppenheimer Separation
- 3. The Electronic Motion
- 4. The Nuclear Motion
- 5. External-Field Effects
- 6. Conclusion
- Appendix A. Bibliography of Theoretical Calculations on the Electronic Structure of the Water Molecule (1925-1970)
- Appendix B. Definition of the Symbols Appearing in TN
- Appendix C. Definition of the Symbols Appearing in Evib and Hrotv
- Appendix D. Definition of the Symbols Appearing in the Rotational Matrix Elements
- 3 Theory of Hydrogen Bonding in Water
- 1. Introduction
- 2. Early Theoretical Studies of the Hydrogen Bond
- 3. Potential Function for the Hydrogen Bond
- 4. Recent Theoretical Methods
- 5. Water Dimer
- 2. Magnetic Shift and Spin Coupling Phenomena in Water Vapor, Water, and Ice
- 3. Measurement and Interpretation of Magnetic Relaxation Times in Water and Ice
- 4. The Contributions of NMR Methods to the Structure Problem in Liquid Water
- 7 Liquid Water: Dielectric Properties
- 1. Introduction
- 2. The Electrical Properties of the Free Water Molecule
- 3. The Measured Static Dielectric Constant
- 4. Theory of the Static Dielectric Constant
- 5. The Static Dielectric Constant Calculated on Various Models
- 6. Interpretation of Static Dielectric Constant with Induced-Dipole Contribution
- 7. Microwave and Submillimeter Dielectric Constants
- 8. Kinks?
- 9. Submillimeter Measurements
- 10. Theory of the Dielectric Constant in a Time-Varying Field
- 11. Interpretation of the Relaxation Times and Absorption Bands
- 12. Interpretation of Data in the Submillimeter Band. Conclusions
- 8 Liquid Water: Scattering of X-Rays
- 1. Introduction
- 2. Experimental Methods
- 2. Ultrasonic Absorption
- 3. Ultrasonic Techniques
- 4. Experimental Results
- 5. Relaxational Compressibility
- 6. Structural Relaxation Time
- 7. Conclusions
- 13 Water at High Temperatures and Pressures
- 1. Introduction
- 2. Thermodynamic Properties
- 3. Transport Properties
- 4. Electrical Properties
- 5. Ionic Product
- 6. Spectroscopic Studies
- 7. Concluding Remarks
- 14 Structural Models
- 1. The Nature of Models
- 2. Requirements a Water Model Must Attempt to Satisfy
- 3. Some Properties of Water of Special Current Interest
- 4. Brief Survey of Models
- 5. The Present „Best Guess“
- References
- 3. Analysis of Diffraction Data
- 4. Diffraction Pattern of Liquid Water
- 5. Conclusions
- 9 The Scattering of Neutrons by Liquid Water
- 1. Introduction
- 2. The Neutron Scattering Method
- 3. Structural Measurements
- 4. Quasielastic Scattering of Neutrons by Water
- 5. Inelastic Scattering of Neutrons by Water
- 6. Discussion
- Appendix. Calculation of Orientational Correlation Factors for Molecules
- 10 Thermodynamic and Transport Properties of Fluid Water
- 1. Introduction
- 2. Thermodynamic Properties
- 3. Transport Properties
- 11 Application of Statistical Mechanics in the Study of Liquid Water
- 1. Introduction
- 2. Characteristic Features of an Effective Pair Potential for Liquid Water
- 3. Application of the Percus-Yevick Equation
- 4. Application of the Monte Carlo Technique
- 5. Some Specific Applications of the Pair Correlation Function
- 12 Liquid Water—Acoustic Properties: Absorption and Relaxation
- 1. Introduction