Cover Image
Read Now

The Physics and Physical Chemistry of Water

to arrive at some temporary consensus model or models; and to present reliable physical data pertaining to water under a range of conditions, i.e., "Dorsey revisited," albeit on a less ambitious scale. I should like to acknowledge a debt of gratitude to several of my col­ leagues, to Prof....

Full description

Bibliographic Details
Other Authors: Franks, Felix (Editor)
Format: eBook
Language:English
Published: New York, NY Springer US 1972, 1972
Edition:1st ed. 1972
Series:Water, a comprehensive treatise
Subjects:
Physical Chemistry
Online Access:
Collection: Springer Book Archives -2004 - Collection details see MPG.ReNa
Table of Contents:
  • 6. Water Polymers
  • 7. Spectroscopic Properties, Proton Potential Functions, Charge Distribution, and Related Aspects
  • 8. Conclusions
  • 4 The Properties of Ice
  • 1. Introduction
  • 2. Phase Behavior of Ice
  • 3. Structures of Crystalline Ice Phases
  • 4. Thermodynamic Properties of Ice Polymorphs
  • 5. Mechanical Properties
  • 6. Lattice Dynamics
  • 7. Molecular and Ionic Transport in Ice
  • 8. Summary
  • 5 Raman and Infrared Spectral Investigations of Water Structure
  • 1. Introduction
  • 2. New Experimental Techniques
  • 3. Intermodular Vibrations of H2O and D2O
  • 4. Intramolecular Vibrational Spectra from H2O in H2O and D2O
  • 5. Intramolecular Vibrational Spectra from H2O and D2O
  • 6. Relation of Component Properties to Water Structure
  • 7. Thermodynamic Tests of the Consecutive Hydrogen-Bond Disruption Model
  • 8. Currentand Future Work
  • 6 Nuclear Magnetic Resonance Studies on Water and Ice
  • 1. Theoretical and Experimental Foundations of Magnetic Resonance
  • 1 Introduction—Water, the Unique Chemical
  • 1. Introduction
  • 2. The Occurrence and Distribution of Water on the Earth
  • 3. Water and Life
  • 4. The Scientific Study of Water—A Short History
  • 5. The Place of Water among Liquids
  • 2 The Water Molecule
  • 1. Introduction
  • 2. Principles of Structure and Spectra: The Born-Oppenheimer Separation
  • 3. The Electronic Motion
  • 4. The Nuclear Motion
  • 5. External-Field Effects
  • 6. Conclusion
  • Appendix A. Bibliography of Theoretical Calculations on the Electronic Structure of the Water Molecule (1925-1970)
  • Appendix B. Definition of the Symbols Appearing in TN
  • Appendix C. Definition of the Symbols Appearing in Evib and Hrotv
  • Appendix D. Definition of the Symbols Appearing in the Rotational Matrix Elements
  • 3 Theory of Hydrogen Bonding in Water
  • 1. Introduction
  • 2. Early Theoretical Studies of the Hydrogen Bond
  • 3. Potential Function for the Hydrogen Bond
  • 4. Recent Theoretical Methods
  • 5. Water Dimer
  • 2. Magnetic Shift and Spin Coupling Phenomena in Water Vapor, Water, and Ice
  • 3. Measurement and Interpretation of Magnetic Relaxation Times in Water and Ice
  • 4. The Contributions of NMR Methods to the Structure Problem in Liquid Water
  • 7 Liquid Water: Dielectric Properties
  • 1. Introduction
  • 2. The Electrical Properties of the Free Water Molecule
  • 3. The Measured Static Dielectric Constant
  • 4. Theory of the Static Dielectric Constant
  • 5. The Static Dielectric Constant Calculated on Various Models
  • 6. Interpretation of Static Dielectric Constant with Induced-Dipole Contribution
  • 7. Microwave and Submillimeter Dielectric Constants
  • 8. Kinks?
  • 9. Submillimeter Measurements
  • 10. Theory of the Dielectric Constant in a Time-Varying Field
  • 11. Interpretation of the Relaxation Times and Absorption Bands
  • 12. Interpretation of Data in the Submillimeter Band. Conclusions
  • 8 Liquid Water: Scattering of X-Rays
  • 1. Introduction
  • 2. Experimental Methods
  • 2. Ultrasonic Absorption
  • 3. Ultrasonic Techniques
  • 4. Experimental Results
  • 5. Relaxational Compressibility
  • 6. Structural Relaxation Time
  • 7. Conclusions
  • 13 Water at High Temperatures and Pressures
  • 1. Introduction
  • 2. Thermodynamic Properties
  • 3. Transport Properties
  • 4. Electrical Properties
  • 5. Ionic Product
  • 6. Spectroscopic Studies
  • 7. Concluding Remarks
  • 14 Structural Models
  • 1. The Nature of Models
  • 2. Requirements a Water Model Must Attempt to Satisfy
  • 3. Some Properties of Water of Special Current Interest
  • 4. Brief Survey of Models
  • 5. The Present „Best Guess“
  • References
  • 3. Analysis of Diffraction Data
  • 4. Diffraction Pattern of Liquid Water
  • 5. Conclusions
  • 9 The Scattering of Neutrons by Liquid Water
  • 1. Introduction
  • 2. The Neutron Scattering Method
  • 3. Structural Measurements
  • 4. Quasielastic Scattering of Neutrons by Water
  • 5. Inelastic Scattering of Neutrons by Water
  • 6. Discussion
  • Appendix. Calculation of Orientational Correlation Factors for Molecules
  • 10 Thermodynamic and Transport Properties of Fluid Water
  • 1. Introduction
  • 2. Thermodynamic Properties
  • 3. Transport Properties
  • 11 Application of Statistical Mechanics in the Study of Liquid Water
  • 1. Introduction
  • 2. Characteristic Features of an Effective Pair Potential for Liquid Water
  • 3. Application of the Percus-Yevick Equation
  • 4. Application of the Monte Carlo Technique
  • 5. Some Specific Applications of the Pair Correlation Function
  • 12 Liquid Water—Acoustic Properties: Absorption and Relaxation
  • 1. Introduction

Similar Items