Modern Aspects of Electrochemistry No. 7

Despite reductions in the level of research activity in most fields which, for reasons of economic decline, have taken place in the U.S. during the last year or two, world progress in the fundamental aspects has continued actively. An important aspect of such recent work has been the use of nonaqueo...

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Bibliographic Details
Main Authors: Conway, B. E., Bockris, J. O'M. (Author)
Format: eBook
Language:English
Published: New York, NY Springer US 1972, 1972
Edition:1st ed. 1972
Subjects:
Online Access:
Collection: Springer Book Archives -2004 - Collection details see MPG.ReNa
Table of Contents:
  • 1 Ionic Solvation in Nonaqueous and Mixed Solvents
  • I. Introduction
  • II. Thermodynamics of Solvation
  • III. Determination of Thermodynamics of Solvation
  • IV. Theoretical Aspects of Solvation
  • V. Solvation Numbers
  • VI. Mixed Solvents
  • VII. Transport Processes
  • References
  • 2 Solvated Electrons in Field- and Photo-Assisted Processes at Electrodes
  • I. Introduction
  • II. Energetic Factors
  • III. Photoassisted Electron Injection from Cathodes
  • IV. Scavenger Behavior in the Electrochemical Photoeffect
  • V. Chemical Evidence for Direct Cathodic Injection of Electrons into Solvents
  • VI. Hydrated Electrons in Aqueous Electrochemical Reactions
  • Acknowledgment
  • References
  • 3 Critical Observations on the Measurement of Adsorption at Electrodes
  • I. Introduction
  • II. Direct Methods of Measuring Adsorption
  • III. Measurement of Surface Tension, Charge, and Capacity
  • IV. Adsorption Indicated by Effects Exerted on Faradaic Processes
  • V. Summary
  • Acknowledgment
  • References
  • 4 Transport-Controlled Deposition and Dissolution of Metals
  • I. Phenomena Involved
  • II. Amplification of Surface Irregularities
  • III. Appearance and Growth of Dendritic Deposits
  • IV. Growth of Whiskers
  • V. Formation of Powdered Deposits
  • VI. Leveling
  • VII. Electropolishing
  • VIII. Deposition of Metals at a Periodically Changing Rate
  • IX. Generalized Model of Transport-Controlled Processes and Approaches to Quantitative Analysis of Its Consequences
  • References
  • 5 Mechanisms of Stepwise Electrode Processes on Amalgams
  • I. Introduction
  • II. Brief Historical Survey
  • III. Processes with a Single Limiting Step
  • IV. Processes with Comparable Rate Constants for Successive Steps
  • V. Application of the Criteria for Stepwise Mechanisms in Some Electrode Redox Reactions
  • References