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140122 ||| eng |
| 020 |
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|a 9781468415308
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| 100 |
1 |
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|a Ebdon, J. R.
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| 245 |
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|a New Methods Polymer Synthesis
|h Elektronische Ressource
|c by J. R. Ebdon
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| 250 |
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|a 1st ed. 1991
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| 260 |
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|a New York, NY
|b Springer US
|c 1991, 1991
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| 300 |
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|a VIII, 200 p
|b online resource
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| 505 |
0 |
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|a 1 Developments in polymerization -- 1.1 Introduction -- 1.2 Radical addition polymerization -- 1.3 Ionic and coordination addition polymerization -- 1.4 Stepwise polymerization -- References -- 2 Group transfer polymerizations -- 2.1 Introduction -- 2.2 Features of group transfer polymerization -- 2.3 Kinetics and mechanism -- 2.4 Aldol group transfer polymerization -- 2.5 Copolymers -- 2.6 Telechelics -- 2.7 Related and anionic polymerizations -- 2.8 Applications -- References -- 3 Ring-opening metathesis polymerization of cyclic alkenes -- 3.1 Scope of ring-opening metathesis polymerization -- 3.2 Monomers for ring-opening metathesis polymerization -- 3.3 Catalysts for the ring-opening polymerization of cycloalkenes -- 3.4 Mechanism of ring-opening metathesis polymerization -- 3.5 Molecular weight distribution in polyalkenylenes -- 3.6 Stereochemistry of ring-opening metathesis polymerization -- 3.7 Thermodynamics of ring-opening polymerization -- References -- 4 Transformation reactions -- 4.1 Introduction -- 4.2 Historical development of transformation reactions -- 4.3 Transformations between anionic and cationic polymerization -- 4.4 Transformations between ionic and free radical polymerization -- 4.5 Transformations involving other modes of polymerization -- 4.6 Conclusions -- References -- 5 Chemical modification of preformed polymers -- 5.1 Introduction -- 5.2 Chemical reactions of polymers: general aspects -- 5.3 Modification of polymers -- References -- 6 Terminally reactive oligomers: telechelic oligomers and macromers -- 6.1 Introduction -- 6.2 The synthesis of terminally reactive oligomers -- 6.3 Reactions and reactivity of telechelic oligomers and macromers -- 6.4 Uses of terminally functionalized oligomers -- References
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| 653 |
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|a Humanities and Social Sciences
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| 653 |
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|a Humanities
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| 653 |
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|a Social sciences
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| 041 |
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7 |
|a eng
|2 ISO 639-2
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| 989 |
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|b SBA
|a Springer Book Archives -2004
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| 028 |
5 |
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|a 10.1007/978-1-4684-1530-8
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| 856 |
4 |
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|u https://doi.org/10.1007/978-1-4684-1530-8?nosfx=y
|x Verlag
|3 Volltext
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| 082 |
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|a 001.3
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| 082 |
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|a 300
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| 520 |
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|a Most practitioners and students of polymer chemistry are familiar, in general terms at least, with the established methods of polymer synthesis - radical, anionic, cationic and coordination addition polymerization, and stepwise con densation and rearrangement polymerization. These methods are used to synthesize the majority of polymers used in the manufacture of commercially important plastics, fibres, resins and rubbers, and are covered in most introduc tory polymer chemistry textbooks and in most undergraduate and graduate courses on polymer science. Fewer polymer chemists, however, have much familiarity with more recent developments in methods of polymer synthesis, unless they have been specifically involved for some time in the synthesis of speciality polymers. These developments include not only refinements to established methods but also new mechanisms of polymerization, such as group transfer and metathesis polymerization and novel non-polymerization routes to speciality polymers involving, for example, the chemical modification of preformed polymers or the linking together of short terminally functionalized blocks
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