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Synthetic Organic Photochemistry

Of all major branches of organic chemistry, I think none has undergone such a rapid, even explosive, development during the past twenty-five years as organic photochemistry. Prior to about 1960, photochemistry was still widely regarded as a branch of physical chemistry which might perhaps have oc­ c...

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Bibliographic Details
Other Authors: Horspool, W.M. (Editor)
Format: eBook
Language:English
Published: New York, NY Springer US 1984, 1984
Edition:1st ed. 1984
Subjects:
Chemistry, Organic
Organic Chemistry
Online Access:
Collection: Springer Book Archives -2004 - Collection details see MPG.ReNa
Table of Contents:
  • 2. Reaction Mechanism
  • 3. Alkene Addends
  • 4. Carbonyl Addends
  • 5. Intramolecular Cycloadditions
  • 6. Chemical Reactions of Oxetans
  • References
  • 9. Equipment and Techniques
  • 1. Mercury Vapor Lamps
  • 2. Lamps in Conjunction with Filters
  • 3. Photochemical Apparatus
  • 4. Actinometry
  • 5. Purity of Solvents and Gases
  • References
  • 5. Photochemical Addition Reactions in the Benzo(b)Thiophene, Benzo(b)Furan, and Indole Series
  • 1. Introduction
  • 2. Photochemistry
  • 3. Benzo(b)thiophene
  • 4. Indoles
  • 5. Benzo(b)thiophenes
  • 6. Benzo(b)furans
  • 7. Thermal Reactions of the 2-Hetero-bicyclo(3.2.0)heptadienes
  • 8. 1,3-Dimethylindole
  • 9. Photocycloadditions of Benzo(b)thiophene to Alkenes
  • References
  • 6. Azirine Photolysis and Cycloaddition Reactions
  • 1. Introduction
  • 2. Cycloaddition Reactions
  • 3. Photodimerization of Azirines
  • 4. Intramolecular Cycloaddition Reactions
  • 5. Mechanisms for Cycloaddition Reactions of Nitrile Ylides
  • 6. Fragmentation Reactions
  • 7. Group Migration Reactions
  • References
  • 7. Photoremovable Protecting Groups
  • 1. Introduction
  • 2. Alcohols
  • 3. Diols
  • 4. Phenols
  • 5. Aldehydes and Ketones
  • 6. Carboxylic Acids and Amides
  • 7. Amines
  • 8. Phosphates
  • 9. Conclusion
  • References
  • 8. Photochemical Synthesis of Oxetans
  • 1. Introduction
  • 1. Photoaddition and Photocyclization Processes of Aromatic Compounds
  • 1. Introduction
  • 2. Intermolecular Reactions
  • 3. Intramolecular Cyclization Processes
  • 2. Enone Photochemical Cycloaddition in Organic Synthesis
  • 1. Introduction
  • 2. The Reaction Mechanism
  • 3. Regiochemistry of Enone Cycloaddition
  • 4. Stereochemistry of Enone Cycloaddition
  • 5. Intramolecular Enone Cycloadditions
  • 6. The de Mayo Reaction
  • 7. Intermolecular Enone Cycloaddition
  • 8. Photochemical Cycloaddition between Enones and Allenes
  • References
  • 3. Synthetic Aspects of Photochemical Electron Transfer Reactions
  • 1. Introduction
  • 2. Reaction Pathways Followed in Electron Transfer Photochemistry
  • 4. Phthalimide and Its Derivatives
  • 1. Introduction
  • 2. Hydrogen Abstraction
  • 3. Reaction with Alkenes
  • 4. Cleavage Reactions
  • 5. Spectra and Excited States
  • 6. Summary
  • References

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