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Reactions of Coordinated Ligands Volume 2

This, the second and final volume of Reactions of Coordinated Ligands, describes the chemistry of ligands bound through non-carbon atoms, and of coordinated carbon dioxide. As before, emphasis is on the underlying mechanisms, which provide a unity of understanding for superficially disparate process...

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Bibliographic Details
Other Authors: Braterman, P.S. (Editor)
Format: eBook
Language:English
Published: New York, NY Springer US 1989, 1989
Edition:1st ed. 1989
Subjects:
Inorganic Chemistry
Chemistry, Organic
Organic Chemistry
Online Access:
Collection: Springer Book Archives -2004 - Collection details see MPG.ReNa
Table of Contents:
  • 1. Reactions of Coordinated Carbon Dioxide
  • 1. Introduction
  • 2. The Properties of Carbon Dioxide
  • 3. Complexes containing CO2 as a Ligand
  • 4. Subsequent reactions of Complexes Containing CO2
  • References
  • 2. Reactions of Coordinated Dinitrogen and Related Species
  • 1. Introduction
  • 2. Methods for Preparing Dinitrogen Complexes
  • 3. Bonding Modes and Charge Distribution of Ligating Dinitrogen
  • 4. Reactions of Ligating Dinitrogen
  • 5. More Recent Results
  • 6. Conclusion
  • References
  • 3. Reactions of Nitrosyls
  • 1. Introduction
  • 2. The Nitroprusside Ion, [Fe(CN)5(NO)]2?, and Related Pentacyanonitrosyls
  • 3. Reduction of Nitrosyls
  • 4. Reactions of Nitrosyls with Nucleophiles
  • 5. Reactions of Nitrosyls with Electrophiles
  • 6. Formation of Carbon-Nitrogen Bonds
  • 7. Coupling, Dimerization and Disproportionation of Nitrogen Monoxide in Nitrosyl Complexes
  • 8. Exchange, Substitution, and Transfer of the Nitrosyl Ligand
  • 9. Miscellaneous Reactions of Nitrosyls
  • References
  • 4. Hydrolysis and Condensation Reactions of O- and N-bound Ligands
  • 1. Introduction
  • 2. Hydrolysis of Amino Acid Esters and Amides, Peptides
  • 3. Condensation Reactions of Amino-Acids Coordinated to Metal Ions
  • 4. Hydrolysis of Carboxylic Esters and Amides
  • 5. Hydrolysis of Nitriles
  • 6. Hydrolysis of Phosphate Esters
  • 7. Hydrolysis of Sulfate Esters
  • 8. Hydrolysis of Epoxides
  • 9. Hydrolysis of Glycosides and Acetals
  • 10. Hydrolysis of Anhydrides
  • 11. Acyl Transfer Reactions
  • 12. Imines
  • 13. Polymer-Metal Complexes
  • 14. More Recent Developments
  • References
  • 5. Reactions of Coordinated Phosphorus and Sulfur Ligands
  • 1. Reactions of Phosphorus and Related Ligands
  • 2. Reactions of Sulfur Ligands
  • References
  • Abbreviations

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