Two Studies in Gas-Phase Ion Spectroscopy Vacuum-Ultraviolet Negative Photoion Spectroscopy and Ion-Molecule Reaction Kinetics

In this thesis Matthew Simpson reports two areas of work in gas ion spectroscopy, each investigation in itself worthy of a PhD. The first study uses tunable vacuum-ultraviolet radiation from a synchrotron to identify negative ions from twenty four photoexcited polyatomic molecules in the gas phase....

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Main Author: Simpson, Matthew J.
Corporate Author: SpringerLink (Online service)
Format: eBook
Language:English
Published: Berlin, Heidelberg Springer Berlin Heidelberg 2012, 2012
Edition:1st ed. 2012
Series:Springer Theses, Recognizing Outstanding Ph.D. Research
Subjects:
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Collection: Springer eBooks 2005- - Collection details see MPG.ReNa
Summary:In this thesis Matthew Simpson reports two areas of work in gas ion spectroscopy, each investigation in itself worthy of a PhD. The first study uses tunable vacuum-ultraviolet radiation from a synchrotron to identify negative ions from twenty four photoexcited polyatomic molecules in the gas phase. From these experiments, Matthew collects a vast amount of data and summarises and reviews ion-pair formation from polyatomic molecules.  The second study is on selected ion flow tube mass spectrometry. Matthew investigates the reactions of cations and anions with ethene, monofluoroethene, 1,1-difluoroethene and tetrafluoroethene. In this study Matthew tries to explain why certain products are formed preferentially over other products at a microscopic level of understanding. The data recorded in this thesis form the most comprehensive collection of information about anion formation and are the basis of a review and numerous articles in specialist journals
Physical Description:XIV, 162 p online resource
ISBN:9783642231292