|
|
|
|
LEADER |
02190nmm a2200301 u 4500 |
001 |
EB001901160 |
003 |
EBX01000000000000001064069 |
005 |
00000000000000.0 |
007 |
cr||||||||||||||||||||| |
008 |
200911 ||| eng |
020 |
|
|
|a 9789811576232
|
100 |
1 |
|
|a Fu, Ming-Chen
|
245 |
0 |
0 |
|a Studies on Green Synthetic Reactions Based on Formic Acid from Biomass
|h Elektronische Ressource
|c by Ming-Chen Fu
|
250 |
|
|
|a 1st ed. 2020
|
260 |
|
|
|a Singapore
|b Springer Nature Singapore
|c 2020, 2020
|
300 |
|
|
|a XIV, 105 p. 189 illus., 24 illus. in color
|b online resource
|
505 |
0 |
|
|a Introduction -- Conversion of Formic Acid as C1 building block on Organic Synthesis -- Non-Metal Boron-Catalyzed N-methylation Conversion of Amines with Formic Acid -- Nickel-Catalyzed Hydrocarboxylation of Alkynes with Formic Acid through Catalytic CO Recycling -- Efficient Pd-Catalyzed Carboxylation of Allylic Alcohols with Formic Acid -- Conclusions
|
653 |
|
|
|a Catalysis
|
653 |
|
|
|a Green chemistry
|
653 |
|
|
|a Chemistry, Organic
|
653 |
|
|
|a Green Chemistry
|
653 |
|
|
|a Organic Chemistry
|
041 |
0 |
7 |
|a eng
|2 ISO 639-2
|
989 |
|
|
|b Springer
|a Springer eBooks 2005-
|
490 |
0 |
|
|a Springer Theses, Recognizing Outstanding Ph.D. Research
|
856 |
4 |
0 |
|u https://doi.org/10.1007/978-981-15-7623-2?nosfx=y
|x Verlag
|3 Volltext
|
082 |
0 |
|
|a 541.395
|
520 |
|
|
|a This book introduces readers to the use of formic acid for efficient organic synthesis. It describes the N-methylation of aromatic and aliphatic amines with formic acid using a boron-based catalyst [B(C6F5)3] in combination with silanes and without the need for an expensive transition metal catalyst. It also shows that formic acid interacts with alkynes and allyl alcohols through a carbonylation process that generates carbon monoxide in situ from nickel and palladium catalysis, respectively, doing away with the need to use high-pressure CO gas and offering a user-friendly and practical method for preparing functionalized α, β- and β, γ-unsaturated carboxylic acids. The findings presented not only enrich the field of ‘C1 chemistry,’ but also support the advancement of green and sustainable chemistry.
|