Functionalization of Carborane via Carboryne Intermediates
This thesis focuses on the development of new methods of functionalizing carboranes using o-carboryne intermediates. Functional carboranes are now finding a broad range of applications, including organic synthesis, drug design, polymers, catalysis, metal−organic frameworks, electronic devices and mo...
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| Format: | eBook |
| Language: | English |
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Singapore
Springer Nature Singapore
2016, 2016
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| Edition: | 1st ed. 2016 |
| Series: | Springer Theses, Recognizing Outstanding Ph.D. Research
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| Collection: | Springer eBooks 2005- - Collection details see MPG.ReNa |
Table of Contents:
- Introduction
- Regioselective Insertion of ο-Carborynes into α-C−H Bond of Tertiary Amines
- Synthesis of Carborane-Functionalized Heterocycles: Dearomative [2 + 2] Cycloaddition and sp2 C–H Insertion Reaction
- Reaction of ο-Carboryne with Nitrones: A Formal [5 + 2] Cycloaddition
- 1,3-Dehydro-ο-Carborane: Generation and Reaction with Arenes
- Ene Reaction of 1,3-Dehydro-ο-Carborane
- Cage Boron Arylation of ο-Carborane via Metal-Free, Visible-Light-Mediated Radical Coupling
- Conclusion
- Experimental Section