Matrix Isolation Spectroscopy

The matrix isolation (MI) method has now been used for nearly thirty years. During this period it has been actively developed and the range of problems tackled greatly extended. Originally it was used for studies of transient species involv­ ing vibrational, electronic and ESR spectroscopy. Nowadays...

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Corporate Author: SpringerLink (Online service)
Other Authors: Barnes, A. (Editor), Orville-Thomas, W.J. (Editor), Gaufrès, R. (Editor), Müller, Achim (Editor)
Format: eBook
Language:English
Published: Dordrecht Springer Netherlands 1981, 1981
Edition:1st ed. 1981
Series:Nato Science Series C:, Mathematical and Physical Sciences
Subjects:
Online Access:
Collection: Springer Book Archives -2004 - Collection details see MPG.ReNa
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100 1 |a Barnes, A.  |e [editor] 
245 0 0 |a Matrix Isolation Spectroscopy  |h Elektronische Ressource  |c edited by A. Barnes, W.J. Orville-Thomas, R. Gaufrès, Achim Müller 
246 3 1 |a A book based on the lectures given and the discussions that took place at the NATO Advanced Study Institute, Université des Sciences et Techniques du Languedoc, Montpellier, France, July 17-31, 1980 
250 |a 1st ed. 1981 
260 |a Dordrecht  |b Springer Netherlands  |c 1981, 1981 
300 |a X, 605 p  |b online resource 
505 0 |a 1. The history of matrix isolation spectroscopy. -- Section A - Techniques -- 2. Infrared and Raman matrix isolation spectroscopy. -- 3. Electronic spectroscopy of matrix isolated solutes. -- 4. Magnetic circular dichroism - matrix isolation spectroscopy. -- 5. Electron spin resonance studies of radicals trapped in rare-gas matrices. -- 6. Mössbauer spectroscopy on matrix-isolated species -- 7. Time and frequency resolved vibrational spectroscopy of matrix isolated molecules: Population and phase relaxation processes. -- 8. Stable molecules. -- 9. Generation and trapping of unstable solutes in low temperature matrices. -- 10. The characterisation of high temperature molecules using matrix isolation and vibrational spectroscopy. -- 11. High pressure studies. -- 12. Non-traditional matrix isolation: adducts. -- Section B - Matrix Effects -- 13. Interpretation of infrared and Raman spectra of trapped molecular impurities from interaction potential calculations. -- 14. Matrix induced changes in the electronic spectra of isolated atoms and molecules. -- 15. Matrix effects studied by electron spin resonance spectroscopy. -- 16. Molecular motion in matrices. -- 17. Vibrational band intensities in matrices. -- Section C - Applications -- 18. Matrix isolation spectroscopy of metal atoms and small clusters. -- 19. Vibrational spectra of matrix isolated gaseous ternary oxides. -- 20. Matrix isolation spectra (IR, Raman) of transition metal compounds. -- 21. Metal carbonyls - structure, photochemistry, and IR lasers. -- 22. Matrix isolation vibrational spectroscopy on organic molecules. -- 23. Conformational isomerism studied by matrix isolation vibrational spectroscopy. -- 24. Hydrogen bonding in matrices. -- Author Index 
653 |a Spectroscopy and Microscopy 
653 |a Spectroscopy 
653 |a Spectroscopy/Spectrometry 
653 |a Microscopy 
700 1 |a Orville-Thomas, W.J.  |e [editor] 
700 1 |a Gaufrès, R.  |e [editor] 
700 1 |a Müller, Achim  |e [editor] 
710 2 |a SpringerLink (Online service) 
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989 |b SBA  |a Springer Book Archives -2004 
490 0 |a Nato Science Series C:, Mathematical and Physical Sciences 
856 |u https://doi.org/10.1007/978-94-009-8540-7?nosfx=y  |x Verlag  |3 Volltext 
082 0 |a 543.2-543.8 
520 |a The matrix isolation (MI) method has now been used for nearly thirty years. During this period it has been actively developed and the range of problems tackled greatly extended. Originally it was used for studies of transient species involv­ ing vibrational, electronic and ESR spectroscopy. Nowadays the study of transient species forms a comparatively small part of HI work since it has been amply demonstrated that very fruitful information can be obtained of the structure and interactions of stable molecules and their aggregates. In addition to the s~ectroscopic methods mentioned above the MI technique is nowadays a standard method in research based on vibrational relaxation, luminescence, Mossbauer, magnetic circular dichroism, pulsed NMR and photoelectron spectroscopy. The matrix isolation technique affords considerable advantages over more conventional methods in most applications of spectroscopy. Areas where the technique has been widely applied, or shows great potential, include: metal atom chemistry, and its relation to surface chemistry, high temperature inorganic species, transition metal complexes, interstellar species, free radicals and unstable molecules, conformational studies, molecular com­ plexes, and intermolecular forces