Principles of Mössbauer Spectroscopy

The emergence of Mossbauer spectroscopy as an important experi­ mental technique for the study of solids has resulted in a wide range of applications in chemistry, physics, metallurgy and biophysics. This book is intended to summarize the elementary principles of the technique at a level appropriate...

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Bibliographic Details
Main Author: Gibb, Terence
Format: eBook
Language:English
Published: Dordrecht Springer Netherlands 1976, 1976
Edition:1st ed. 1976
Series:Studies in Chemical Physics
Subjects:
Online Access:
Collection: Springer Book Archives -2004 - Collection details see MPG.ReNa
Table of Contents:
  • 4.5 Covalent iron compounds
  • References
  • 5 Electronic Structure and Bonding:Paramagnetic Compounds
  • 5.1 Quadrupole interactions
  • 5.2 Magnetic hyperfine interactions
  • 5.3 Spin cross-over
  • 5.4 Pressure effects
  • 5.5 Second and third row transition elements
  • 5.6 Lanthanides and actinides
  • References
  • 6 Dynamic Effects
  • 6.1 Second-order Doppler shift and recoilless fraction
  • 6.2 The Gold an skii-Karyagin effect
  • 6.3 Electron hopping and atomic diffusion
  • 6.4 Paramagnetic relaxation
  • 6.5 Superparamagnetism
  • References
  • 7 Oxides and Related Systems
  • 7.1 Stoichiome tric spinels
  • 7.2 Non-stoichiometric spinels
  • 7.3 Exchange interactions in spinels
  • 7.4 Rare-earth iron garnets
  • 7.5 Transferred hyperfine interactions
  • References
  • 8 Alloys and Intermeiallic Compounds
  • 8.1 Disordered alloys
  • 8.2 Intermetallic compounds
  • References
  • 9 Analytical Applications
  • 9.1 Chemical analysis
  • 9.2 Silicate minerals
  • 9.3 Surface chemistry
  • 1 The Mossbauer Effect
  • 1.1 Resonant absorption and fluorescence
  • 1.2 The Mossbauer effect
  • 1.3 The Mossbauer spectrum
  • 1.4 The Mossbauer spectrometer
  • 1.5 Mossbauer isotopes
  • 1.6 Computation of data
  • References
  • 2 Hyperfine Interactions
  • 2.1 The chemical isomer shift
  • 2.2 Magnetic hyperfine interactions
  • 2.3 Electric quadrupole interactions
  • 2.4 Combined magnetic and quadrupole interactions
  • 2.5 Relative line intensities
  • References
  • 3 Molecular Structure
  • 3.1 Iron carbonyls and derivatives
  • 3.2 Geometrical isomerism in Fe and Sn compounds
  • 3.3 Linkage isomerism in cyano-complexes of Fe
  • 3.4 Conformations in organometallic compounds of Fe
  • 3.5 Stereochemistry in tin compounds
  • 3.6 Molecular iodine compounds
  • Appendix Quadrupole splitting in cis- and trans-isomers
  • References
  • 4 Electronic Structure and Bonding: Diamagnetic Compounds
  • 4.1 Formal oxidation state
  • 4.2 Iodine
  • 4.3 Tellurium and antimony
  • 4.4 Tin
  • References
  • 10 Impurity and Decay After-effect Studies
  • 10.1 Impurity doping
  • 10.2 Decay after-effects
  • References
  • 11 Biological Systems
  • 11.1 Haemoproteins
  • 11.2 Ferredoxins
  • References
  • Observed Mossbauer Resonances