|
|
|
|
| LEADER |
06618nmm a2200325 u 4500 |
| 001 |
EB000669214 |
| 003 |
EBX01000000000000000522296 |
| 005 |
00000000000000.0 |
| 007 |
cr||||||||||||||||||||| |
| 008 |
140122 ||| eng |
| 020 |
|
|
|a 9783642668272
|
| 100 |
1 |
|
|a Epiotis, N. D.
|
| 245 |
0 |
0 |
|a Theory of Organic Reactions
|h Elektronische Ressource
|c by N. D. Epiotis
|
| 250 |
|
|
|a 1st ed. 1978
|
| 260 |
|
|
|a Berlin, Heidelberg
|b Springer Berlin Heidelberg
|c 1978, 1978
|
| 300 |
|
|
|a XIV, 290 p
|b online resource
|
| 505 |
0 |
|
|a 1. One-Determinental Theory of Chemical Reactivity -- 1.1 General Principles and Computational Schemes -- 1.2 Qualitative One-Determinental Models of Chemical Reactivity -- 1.3 The Static One Electron Molecular Orbital Model -- 1.4 Orbital Energies. The Donor-Acceptor Classification of Molecules and the Concept of Reaction Polarity -- 1.5 One Electron Interaction Matrix Elements and Overlap Integrals -- 1.6 The Woodward-Hoffmann Molecular Orbital Correlation Diagram -- 2. Configuration Interaction Overview of Chemical Reactivity -- 2.1 General Principles -- 2.2 Qualitative Configuration Interaction Models of Chemical Reactivity -- 2.3 The Static Linear Combination of Fragment Configurations Method -- 2.4 The Static Delocalized Configuration Interaction Method -- 2.5 The Dynamic Delocalized Configuration Interaction Method -- 3. The Dynamic Linear Combination of Fragment Configurations Method -- 3.1 Definitions -- 3.2 General Theoretical Considerations --
|
| 505 |
0 |
|
|a 7.5 ??* State Dual Channel Mechanisms of Polar Nonionic Photocycloadditions -- 8. Miscellaneous Intermolecular Multicentric Reactions -- 8.1 Cycloadditions of Cumulene Systems -- 8.2 The Ene Reaction -- 8.3 1,3 Dipolar Cycloadditions -- 9. ?? A ddition Reactions -- 9.1 Introduction -- 9.2 Potential Energy Surfaces for 2?+2? Additions -- 9.3 Reactivity Trends of 2?+2? Additions -- 10. Even-Odd Multicentric Intermolecular Reactions -- 10.1 Potential Energy Surfaces for 2?+1? Cycloadditions -- 10.2 Reactivity Trends of Cationic Even-Odd Retro-Cycloadditions and Eliminations -- 11. Potential Energy Surfaces for Odd-Odd Multicentric IntermolecularReactions -- 12. Even-Even Intermolecular Bicentric Reactions -- 12.1 Potential Energy Surfaces for Electrophilic and Nucleophilic Additions -- 12.2 Reactivity Trends of Electrophilic and Nucleophilic Substitutions -- 13. Even-Odd Intermolecular Bicentric Reactions -- 13.1 Potential Energy Surfaces for Radical Additions --
|
| 505 |
0 |
|
|a 4.11 The Effect of Low Lying Diexcited Diabatic Surfaces in Photoreactions -- 4.12 The Problem of Energy Wastage. The Concept of Dual Channel Photoreactions -- 4.13 Generalizations -- 5. The Problem of Correlation Imposed Barriers -- 6. Reactivity Trends of Thermal Cycloadditions -- 6.1 Introduction -- 6.2 Mechanisms of Stereochemical Nonretention in Cycloadditions -- 6.3 Reactivity Trends of Thermal Nonionic 2?+2? Cycloadditions -- 6.4 Reactivity Trends of Thermal Ionic 2?+2? Cycloadditions -- 6.5 The 2?+2? Ionic Cycloaddition Problem -- 6.6 Reactivity Trends of Thermal Nonionic 4?+2? Cycloadditions -- 6.7 Reactivity Trends of Thermal Ionic 4?+2? Cycloadditions -- 7. Reactivity Trends of Singlet Photochemical Cycloadditions -- 7.1 Introduction -- 7.2 The Chorochemistry of Singlet 2?+2? Photocycloadditions -- 7.3 “Unusual” Head to Head vs. Head to Tail Regioselectivity of Photocycloadditions -- 7.4 n?* State Dual Channel Mechanisms of Polar Nonionic Carbonyl Photocycloadditions --
|
| 505 |
0 |
|
|a 13.2 Reactivity Trends of Radical Substitution Reactions -- 14. Odd-Odd Intermolecular Bicentric Reactions. Potential Energy Surfaces for Geometric Isomerization and Radical Combination -- 15. Odd-Odd Intramolecular Multicentric Reactions -- 15.1 Potential Energy Surfaces for Sigmatropic Shifts -- 15.2 Reactivity Trends of Sigmatropic Shifts -- 16. Even-Even Intramolecular Multicentric Reactions -- 16.1 Potential Energy Surfaces for Ionic Rearrangements -- 16.2 Reactivity Trends of Ionic Rearrangements -- 17. Mechanisms of Electrocyclic Reactions -- 17.1 Introduction -- 17.2 Reactivity Trends of Electrocyclic Reactions -- 18. Triplet Reactivity -- 18.1 Introduction -- 18.2 Excited State Spin Multiplicity and Photochemical Barrier Heights -- 18.3 The Mechanism of Spin Inversion in Triplet Nonionic Photoaromatic Reactions -- 18.4 The Mechanism of Spin Inversion in Triplet Nonionic Photoantiaromatic Reactions -- 18.5 Spin-Orbit Coupling Borrowing --
|
| 505 |
0 |
|
|a 18.6 Mechanisms of Triplet Photoreactions -- 18.7 A Model of Triplet Reactivity -- 18.8 Spin-Orbit Coupling and the Chorochemistry of Triplet Photocycloadditions -- 18.9 Spin-Orbit Coupling and the Regiochemistry of Triplet Photoaromatic Substitutions -- 19. Photophysical Processes -- 20. The Importance of Low Lying Nonvalence Orbitals -- 21. Divertissements -- 21.1 Thermal Antiaromatic Pericyclic Reactions -- 21.2 Induced Thermal Pericyclic Reactions -- 21.3 Half-Aromatic Reaction Paths -- 21.4 Ambident Reactivity -- 21.5 The Stereoselectivity of Photocycloadditions: In Search of Antiaromatic Intermediates -- 22. A Contrast of “Accepted” Concepts of Organic Reactivity and the Present Work -- Epilogue -- References -- Author Index
|
| 505 |
0 |
|
|a 3.3 The Interaction of Diabatic Surfaces -- 3.4 Polarity Control of Barrier Heights and Decay Efficiencies -- 3.5 The Effect of Excitation Energy on Photochemical Barrier Height -- 3.6 Diabatic Surface Interrelationships. A Classification of Chemical Reactions -- 4. Even-Even Intermodular Multicentric Reactions -- 4.1 Potential Energy Surfaces for 2?+2? Cycloadditions -- 4.2 The Effect of Polarity. Potential Energy Surfaces for Nonionic and Ionic In 2?+2? Cycloadditions -- 4.3 Pericyclic, Effectively Pericyclic and Quasipericyclic Reactions -- 4.4 The Effect of Unsymmetrical Substitution and the Effect of Conjugative Substitution -- 4.5 The Regiochemistry of 2?+2? Cycloadditions -- 4.6 Isomeric Reactions and the Topochemistry of 2?+2? Cycloreversions -- 4.7 The Topochemistry of Intramolecular Cycloadditions -- 4.8 The Selectivity-PolarityRelationship -- 4.9 Reaction Intermediates and Types of Organic Mechanisms -- 4.10 2?+2? Nonionic Photocycloadditions Involving n?* Excitation --
|
| 653 |
|
|
|a Chemistry, Organic
|
| 653 |
|
|
|a Organic Chemistry
|
| 041 |
0 |
7 |
|a eng
|2 ISO 639-2
|
| 989 |
|
|
|b SBA
|a Springer Book Archives -2004
|
| 490 |
0 |
|
|a Reactivity and Structure: Concepts in Organic Chemistry
|
| 028 |
5 |
0 |
|a 10.1007/978-3-642-66827-2
|
| 856 |
4 |
0 |
|u https://doi.org/10.1007/978-3-642-66827-2?nosfx=y
|x Verlag
|3 Volltext
|
| 082 |
0 |
|
|a 547
|