Chlorine, Bromine and Iodine NMR Physico-Chemical and Biological Applications

The increasing interest in NMR spectroscopy of what in some confer­ ences in this field is commonly termed "other nuclei" is unmistakable. Chemists and biologists who employ NMR spectroscopy to study their problems have, however, been somewhat reluctant to study nuclei with electric quadru...

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Main Authors: Lindman, B., Forsen, S. (Author)
Corporate Author: SpringerLink (Online service)
Format: eBook
Language:English
Published: Berlin, Heidelberg Springer Berlin Heidelberg 1976, 1976
Edition:1st ed. 1976
Series:NMR Basic Principles and Progress
Subjects:
Online Access:
Collection: Springer Book Archives -2004 - Collection details see MPG.ReNa
Table of Contents:
  • 1. Introductory Aspects
  • 1.1 General Properties of Halogens
  • 1.2 Static Parameters
  • 1.3 Dynamic Parameters
  • 1.4 Chemical Exchange Effects
  • 1.5 Experimental Aspects
  • 2. Relaxation in Molecules or Ions With Covalently Bonded Halogens
  • 2.1 Quadrupole Relaxation
  • 2.2 Other Relaxation Mechanisms
  • 3. Shielding Effects in Covalent Halogen Compounds
  • 3.1 Theoretical Aspects
  • 3.2 Experimental Data
  • 3.3 Medium Effects on Halogen Shielding Constants
  • 4. Scalar Spin Couplings
  • 4.1 General Considerations
  • 4.2 Experimental Data on Cl, Br and I Spin Couplings
  • 5. Relaxation of Chloride, Bromide and Iodide Ions
  • 5.1 Quadrupole Relaxation
  • 5.2 Relaxation Rates and Chemical Shifts in Paramagnetic Systems
  • 5.3 Chemical Exchange of Halide Ions
  • 6. Shielding of Halide Ions
  • 6.1 Absolute Shielding Values of Ions in Aqueous Solutions
  • 6.2 Shielding in Aqueous Alkali Halide Solutions
  • 6.3 Shielding in Other Aqueous Solutions
  • 6.4 Shielding in Mixed Solvent an