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Aqueous Solutions of Simple Electrolytes

The chapters making up this volume had originally been planned to form part of a single volume covering solid hydrates and aqueous solutions of simple molecules and ions. However, during the preparation of the manu­ scripts it became apparent that such a volume would turn out to be very unwieldy and...

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Bibliographic Details
Main Author: Franks, Felix
Format: eBook
Language:English
Published: New York, NY Springer US 1973, 1973
Edition:1st ed. 1973
Series:Water, a comprehensive treatise
Subjects:
Physical Chemistry
Online Access:
Collection: Springer Book Archives -2004 - Collection details see MPG.ReNa
Table of Contents:
  • 1 Thermodynamics of Ion Hydration
  • 1. The Thermodynamic Theory of Solvation
  • 2. Molecular Interpretation
  • 3. Hydration of Gaseous Ions
  • 4. Other Thermodynamic Properties of Ions at Infinite Dilution in Water
  • 5. Solvent-Isotope Effect in Hydration
  • 6. Reference Solvents
  • 7. Ionic Hydration and Excess Properties
  • 2 Thermodynamics of Aqueous Mixed Electrolytes
  • 1. Introduction
  • 2. Theoretical Framework
  • 3. Experimental Techniques
  • 4. Experimental Results and Discussion
  • 3 Hydration Effects and Acid-Base Equilibria
  • 1. Ionization of Liquid Water
  • 2. Hydration of H+ and OH?
  • 3. Organic Acids and Bases in Aqueous Solution
  • 4 Ionic Transport in Water and Mixed Aqueous Solvents
  • 1. Introduction
  • 2. Measurement
  • 3. Limiting Ionic Conductances in Binary Solutions
  • 4. Mechanism of Ionic Conductance
  • 5. Limiting Ionic Conductance in Aqueous Solvent Mixtures
  • 5 Infrared Spectroscopy of Aqueous Electrolyte Solutions
  • 1. Introduction
  • 2. Information on Aqueous Ionic Solutions Obtainable from Infrared Analysis
  • 3. Experimental Methods
  • 4. Critical Review of Available Infrared Data
  • 5. Conclusion
  • 6 Raman Spectroscopy of Aqueous Electrolyte Solutions
  • 1. Discussion
  • 2. Raman Bands Arising from Solutes
  • 3. Raman Bands Arising from the Solvent: Liquid Water
  • 4. Addendum
  • 7 Nuclear Magnetic Relaxation Spectroscopy
  • 1. Introduction
  • 2. Nuclear Magnetic Relaxation
  • 8 Dielectric Properties
  • 1. Basic Theory
  • 2. Experimental Methods
  • 3. Characteristic Quantities Derived from Complex Permittivity Measurements
  • 4. Information from the “Static” Permittivity
  • 5. Information Obtainable from the Dielectric Relaxation Time with the Help of the Proton Magnetic Relaxation Rate
  • 6. The Influence of Small Cations on the Dielectric Relaxation Time
  • 7.Summary
  • References
  • Compound Index
  • Formula Index

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