Dipole Moments in Organic Chemistry
In accordance with the aims of the series "Physical Methods in Organic Chemistry," of which this book forms part, the authors r main aim was a systematic account of the most important methods of using the method of dipole moments in organic chemistry and interpreting its results in practic...
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| Format: | eBook |
| Language: | English |
| Published: |
New York, NY
Springer US
1970, 1970
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| Edition: | 1st ed. 1970 |
| Series: | Physical Methods in Organic Chemistry
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| Subjects: | |
| Online Access: | |
| Collection: | Springer Book Archives -2004 - Collection details see MPG.ReNa |
Table of Contents:
- VI Dipole Moments and Some Special Problems of the Structure and Properties of Organic Compounds
- 1. Tautomerism
- 2. The Hydrogen Bond
- 3. Intermolecular Interactions
- 4. Dipole Moments of Molecules in Electronically Excited States
- 5. Literature Cited
- I Basic Principles of the Theory of Dielectrics
- 1. Behavior of a Dielectric in a Static Electric Field
- 2. Molecular Polarizability
- 3. Statistical Theory of the Polarization of Polar Liquid Dielectrics
- 4. Dielectric Properties of a Substance in a Variable Electric Field
- 5. Literature Cited
- II Nature of the Dipole Moment and Methods For Its Determination
- 1. Nature of the Dipole Moment
- 2. Methods of Determining Dipole Moments
- 3. Determination of the Dipole Moment in the Vapor Phase
- 4. Determination of the Dipole Moment in Dilute Solutions (Debye’s Second Method)
- 5. Solvent Effect
- 6. Determination of the Dipole Moment by Means of the Stark Effect
- 7. Electric Resonance Method of Determining Dipole Moments
- 8. Determination of Dipole Moments of Liquids by Measuring Dielectric Losses in the Microwave Region
- 9. Literature Cited
- III Calculations in the Dipole Moment Method
- 1. Bond and Group Moments
- 2. Vectorial Additive Method for Calculating Dipole Moments of Molecules from Bond and Group Moments
- 3. Critical Observations on the Vectorial Additive Scheme and Methods for Its Improvement
- 4. Quantum-Mechanical Calculations of the Dipole Moments of Complex Molecules
- 5. Literature Cited
- IV Dipole Moments and the Stereochemistry of Organic Compounds
- 1. The Dipole Moment and the Symmetry of the Molecule
- 2. Geometrical cis-trans Isomerism Relative to Double Bonds
- 3. s-cis-trans Isomerism
- 4. Nonplanar Conformations of Aryl Nuclei in Uncondensed Aromatic Systems
- 5. Conformational Analysis of Saturated Cyclic Systems
- 6. Internal Rotation Relative to Single Bonds
- 7. Literature Cited
- V Dipole Moments and the Electronic Structure of Organic Compounds
- 1. Induction Effect
- 2. Conjugation of an Unsaturated System with Polar Groups.Mesomeric Moments. Interaction Moments
- 3. Dipole Moments and Intramolecular Polarization
- 4. Literature Cited