Photoelectrochemistry
Other Authors: | |
---|---|
Format: | eBook |
Language: | English |
Published: |
New York, NY
Springer US
1980, 1980
|
Edition: | 1st ed. 1980 |
Subjects: | |
Online Access: | |
Collection: | Springer Book Archives -2004 - Collection details see MPG.ReNa |
Table of Contents:
- 3.5. The Choice of Acceptors for Solvated Electrons
- 4. Photoelectron Emission in Solutions: Its Discovery, Kinetics, and Energetics
- 4.1. Introductory Notes
- 4.2. The Dependence of the Photoemission Current on the Electrode Potential and Quantum Energy. Experimental Verification of the 5/2 Power Law
- 4.3. The Effect of the Nature of the Metal on Photoemission and Electrochemical Kinetics
- 4.4. Energetics of Excess Electrons in Polar Solvents
- 4.5. The Effect of the Light Frequency and Polarization. Bulk andSurface Excitation of Electrons
- 4.6. Multiphoton Emission
- 5. Emitted Electrons in Solution: Subsequent Transformations
- 5.1. Dependence of the Photocurrent on Acceptor Concentration
- 5.2. Is There a Contribution of “Dry” Electrons to Photodiffusion Currents?
- 5.3. Characteristics of Retardation and Hydration of Photoelectrons
- 5.4.Slow Capture of Hydrated Electrons by the Metal Surface
- 0.1. Historical Background
- 0.2. Stages of Photoelectron Emission into Solution
- 0.3. General Features of Emission Phenomena in Electrochemical Systems
- 1. Fundamentals of the Theory of Photoelectron Emission from Metals into Solutions
- 1.1. Qualitative Description of the Phenomenon
- 1.2. The Threshold Approach to Photoemission
- 1.3. Calculation of the Photoemission Current
- 1.4. The 5/2 Power Law
- 1.5. The Effects of the Double Layer on the Photoemission
- 1.6. Dependence of the Photoemission Current on the Characteristics of the Irradiation
- 2. Theory of Photodiffusion Currents
- 2.1. Formulation of the Problem and Basic Relations
- 2.2. Stationary Photodiffusion Currents
- 2.3. Alternating Photodiffusion Currents
- 3. Experimental Techniques in Photoemission Studies
- 3.1. General Discussion of Photocurrent Measurements
- 3.2. Measuring Apparatus
- 3.3. Electrode Illumination
- 3.4. Electrochemical Cells
- 5.5. Measurements of the Rate Constants of Electron Capture by Acceptors
- 5.6. Method of Competing Acceptors in Photoemission Studies
- 6. Investigation of the Structure of the Electric Double Layer Using the Photoemission Method
- 6.1. The Role of the Diffuse Layer in Photoemission Phenomena; General Considerations
- 6.2. Dependence of the Photocurrent on Electrolyte Concentration
- 6.3. Measurement of the Potential of Zero Charge by a Photoemission Method
- 6.4. Direct Experimental Determination of the ? Potential
- 6.5. Investigation of Specific Adsorption
- 6.6. Evaluation of the Thickness of the Compact Layer
- 7. Photoemission As a Method of Investigation of Electrochemical Kinetics: Processes Involving Atomic Hydrogen
- 7.1. Formation of Atomic Hydrogen in Electrochemical Reactions. Phenomenology and Empirical Equations
- 7.2. Basic Experimental Data Concerning Atomic Hydrogen Reactions
- 7.3. The Role of the Adsorption Stage
- 7.4. The Mechanism of Atomic Hydrogen Reactions on Mercury Electrodes
- 7.5. The Mechanism of Atomic Hydrogen Reactions at Bismuth and Other Solid Electrodes
- 7.6. The Effect of the Double Layer on the Kinetics of Atomic Hydrogen Reactions
- 8. Photoemission As a Method of Investigating Homogeneous Reactions Involving Free Radicals
- 8.1. Chemical and Electrochemical Reactions of the Radical Anion NO32-
- 8.2. Chemical and Electrochemical Reactions Involving CO2? and CH3° Radicals
- 8.3. Chemical Reactions of H and OH Radicals with Alcohols and Other Organic Compounds
- 8.4. Multielectron Electrochemical Reactions Initiated by Photoemission
- 9. Photoelectron Emission from Semiconductors into Solutions and from Solutions into the Vapor Phase
- 9.1. Qualitative Description ofPhotoemission from Semiconductors
- 9.2. Calculation of the Photoemission Current at Semiconductor Electrodes
- 9.3. Photoemission from Semiconductor Electrodes: Experimental
- 9.4. Photoelectron Emission from Solutions into the Vapor Phase. Schematic Aspects of the Process
- 9.5. Principles of the Theory of Photoelectron Emission from Solutions
- 9.6. Photoelectron Emission from Solutions. Basic Experimental Results
- 10. Specific Problems of Photoelectrochemical Phenomena
- 10.1. Currents of Photoelectrochemical Reactions
- 10.2. Currents of the Pulse Warm-Up of the Electrode
- 10.3. Cathodic Generation of Solvated Electrons. Is the Solvated Electron an Intermediate in Cathodic Reactions?
- 10.4. Photoelectrochemical Effects Due to Surface Plasmons
- 10.5. Photoemission into Various Media
- 11. Perspectives of Photoemission Studies
- Appendixes
- References