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Coordination Chemistry of Macrocyclic Compounds

Chemists have been aware of the existence of coordination compounds con­ taining organic macrocyclic ligands since the first part of this century ; however, only during the past few years have they expanded research into the chemistry of these compounds. The expansion was initiated in the early 1960...

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Bibliographic Details
Other Authors: Melson, Gordon (Editor)
Format: eBook
Language:English
Published: New York, NY Springer US 1979, 1979
Edition:1st ed. 1979
Subjects:
Inorganic Chemistry
Online Access:
Collection: Springer Book Archives -2004 - Collection details see MPG.ReNa
Table of Contents:
  • 5. Comments on Vitamin B12 and Related Inorganic Systems
  • References
  • Dibenzo[b,i]-l,4,8,11-tetraazacyclotetradec-2,4,6,9,11-hexaenato(2–) Compounds
  • 7. Class 6: Cyclic Hydrazines and Hydrazones
  • 8. Class 7: Cyclic Tetraethers and Tetrathiaethers (Tetraoxo- and Tetrathiamacrocycles)
  • 9. Class 8: Macrocycles with More Than One Type of Heteroatom
  • 10. Class 9: Binucleating Macrocycles
  • 11. Class 10: Cyclic Phosphazenes
  • 12. Class 11: Clathrochelates
  • 13. Conclusion
  • References
  • 5. Ligand Field Spectra and Magnetic Properties of Synthetic Macrocyclic Complexes
  • 1. Introduction
  • 2. Nickel Complexes
  • 3. Copper Complexes
  • 4. Cobalt Complexes
  • 5. Iron Complexes
  • 6. Manganese Complexes
  • References
  • 6. Chemical Reactivity in Constrained Systems
  • 1. Introduction
  • 2. Predominantly Metal-Centered Reactions
  • 3. Reactions of the Macrocyclic Ligands
  • 4. Reactions Involving Free Radicals, Unusual Oxidation States, and Excited States
  • References
  • 7. Metal Complexes of Phthalocyanines
  • 1. Introduction
  • Preparation and Structure
  • 4. Complexes in Solutions: Experimental Techniques
  • 5. Conclusion
  • References
  • 10. Natural-Product Model Systems
  • 1. Introduction
  • 2. Macrocyclic Complexes as Models
  • 3. Modeling of Heme Proteins
  • 4. Binuclear Systems
  • Cyclic Amines-Saturated Polyaza Macrocycles
  • 3. Class 2: Cyclic Imines and Cyclic Amine-Imines (Unsaturated Polyaza Macrocycles with all Nitrogen Atoms Coordinated)
  • 4. Class 3: Macrocycles Including a 2,6-Pyridyl Group
  • 5. Class 4: Tetraazamacrocycles with 2-Imino(or 2-amido)-benzaldimine Chelate Rings

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