Cover Image
Read Now

Organic Syntheses by Oxidation with Metal Compounds

This book is concerned with the synthetic aspects of oxidation reactions involving metal compounds. which are readily available or easy to prepare. The sequence followed in the chapters is as follows: a general introduction. a limited treatment of reaction mechanisms to serve as a basis for synthesi...

Full description

Bibliographic Details
Other Authors: Mijs, W.J. (Editor), de Jonge, C.R.H.I. (Editor)
Format: eBook
Language:English
Published: New York, NY Springer US 1986, 1986
Edition:1st ed. 1986
Subjects:
Chemistry, Organic
Organic Chemistry
Online Access:
Collection: Springer Book Archives -2004 - Collection details see MPG.ReNa
Table of Contents:
  • 3. Scope and Limitations
  • 4. Experimental Considerations and Procedures
  • References
  • 13. Thallium(IH) Salts as Oxidants in Organic Synthesis
  • 1. Introduction
  • 2. Scope and Limitations
  • 3. Experimental Considerations and Procedures
  • References
  • 14. Oxidations with Lead Tetraacetate
  • 1. Introduction
  • 2. Hydrocarbons
  • 3. Monohydroxylic Alcohols
  • 4. 1,2-Diols and Polyols
  • 5. Phenols
  • 6. Carbonyl Compounds
  • 7. Carboxylic Acids
  • 8. Nitrogen-Containing Compounds
  • 9. Experimental Considerations and Procedures
  • 10. Addendum
  • References
  • 15. Bismuth-Salt Oxidations
  • 1. Introduction
  • 2. Sodium Bismuthate Oxidations
  • 3. Bismuth Trioxide Oxidations
  • 4. Organobismuth Reagents
  • 5.The Toxicity of Bismuth
  • References
  • 16. Oxidations with Metal Compounds and Peroxides
  • 1. Introduction
  • 2. Mechanism
  • 3. Scope and Limitations
  • 4. Experimental Considerations and Procedures
  • References
  • 1. Oxidation by Vanadium Compounds
  • 1. Introduction
  • 2. Mechanisms
  • 3.Scope and Limitations
  • 4.Experimental Considerations and Procedures
  • References
  • 2. Oxidation by Oxochromium(VI) Compounds
  • 1. Introduction
  • 2. Mechanisms
  • 3.Scope and Limitations
  • 4.Experimental Considerations and Procedures
  • References
  • 3. The Oxidation of Organic Compounds by Active Manganese Dioxide
  • 1.Introduction
  • 2.Mechanism
  • 3.Oxidation of Alcohols and Hydroxy Compounds
  • 4.Dehydrogenation and Oxidative Aromatization
  • 5.Hydrocarbons
  • 6.Amines and Hydrazines
  • 7.Miscellaneous Oxidations
  • 8.Experimental Procedures
  • References
  • 4. Reactions with Manganese(III) Acetate
  • 1. Introduction
  • 2. Synthesis and Properties of Manganese (III) Acetate
  • 3. Oxidative Addition Reactions of Acids to Olefinic Unsaturated Systems
  • 4. Mn(III) Acetate-Initiated Addition of Aldehydes to Olefinic Unsaturated Systems
  • 8. Ruthenium Tetroxide Oxidations
  • 1. Introduction
  • 2. The Mechanism of Ruthenium Tetroxide Oxidations
  • 3. Scope and Limitations
  • 4. Experimental Considerations and Procedures
  • References
  • 9. Oxidations Using Palladium Compounds
  • 1. Introduction
  • 2. Oxidation of Olefins
  • 3. Vinylic Substitution Reactions
  • 4. Aromatic Substitution Reactions
  • 5. Oxidative Carbonylations
  • 6. Some Reactions of Alcohols
  • 7. Examples
  • References
  • 10. Silver Carbonate on Celite Oxidations
  • 1. Introduction
  • 2. Mechanism
  • 3. Scope and Limitations
  • 4. Experimental Procedures
  • References
  • 11. Cerium(IV) Oxidation of Organic Compounds
  • 1. Introduction
  • 2. Mechanism
  • 3. Scope and Limitations
  • Note Added in Proof
  • 4. Experimental Conditions and Procedures
  • 5. Tabular Survey of Oxidation Reactions
  • References
  • 12. Oxidations of Organic Compounds with Osmium Tetroxide
  • 1. Introduction
  • 2. General Mechanism of Osmium Tetroxide Oxidation Reactions
  • 5. Mn(III) Acetate-Initiated Addition of Ketones to Olefinic Unsaturated Systems
  • 6. Mn(III) Acetate-Acetone - Initiated Addition of Haloalkanes to Unsaturated Systems
  • 7. Aromatic Substitution Reactions
  • 8. Direct Oxidation Reactions with Manganese (III) Acetate
  • 9. Synthetic Procedures
  • References
  • 5. Oxidations by Cobalt Compounds
  • 1. Introduction
  • 2. Mechanisms
  • 3. Scope and Limitations
  • 4. Experimental Considerations and Procedures
  • References
  • 6. Oxidation of Organic Compounds with Nickel Peroxide
  • 1. Introduction
  • 2. Mechanism of Oxidation
  • 3. Scope and Limitations
  • 4. Experimental Considerations
  • References
  • 7. Oxidations of Organic Compounds Catalyzed by Copper- and Cobalt-Amine Complexes
  • 1. Introduction
  • 2. Mechanism
  • 3. Scope and Limitations
  • 4. Experimental Considerations and Procedures
  • 5. Tabular Survey of Oxidations of Organic Compounds Catalyzed by Copper- and Cobalt-Amine Complexes
  • References

Similar Items