New Discoveries on the β-Hydride Elimination

The work presented in Thomas M. Gøgsig's thesis deals with the discovery of new metal-catalyzed transformations ranging from Kumada-, Heck- and Suzuki-type reactions. The thesis starts with a formidable introduction to Pd-catalyzed cross-coupling reactions. New results have been obtained on: (i...

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Bibliographic Details
Main Author: Gøgsig, Thomas M.
Format: eBook
Language:English
Published: Berlin, Heidelberg Springer Berlin Heidelberg 2012, 2012
Edition:1st ed. 2012
Series:Springer Theses, Recognizing Outstanding Ph.D. Research
Subjects:
Online Access:
Collection: Springer eBooks 2005- - Collection details see MPG.ReNa
Table of Contents:
  • Background
  • Palladium 1,2-migration in the Heck reaction
  • Palladium 1,2-migration in the Negishi and Kumada coupling
  • Stoichiometric studies on the palladium 1,2-migration
  • Heteroaromatic tosylates in the regio-selective Heck reaction
  • Cationic intermediates in the Ni(0)-catalyzed Heck reaction
  • Carbonylative Heck reaction
  • Conclusions