New Discoveries on the β-Hydride Elimination
The work presented in Thomas M. Gøgsig's thesis deals with the discovery of new metal-catalyzed transformations ranging from Kumada-, Heck- and Suzuki-type reactions. The thesis starts with a formidable introduction to Pd-catalyzed cross-coupling reactions. New results have been obtained on: (i...
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Format: | eBook |
Language: | English |
Published: |
Berlin, Heidelberg
Springer Berlin Heidelberg
2012, 2012
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Edition: | 1st ed. 2012 |
Series: | Springer Theses, Recognizing Outstanding Ph.D. Research
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Subjects: | |
Online Access: | |
Collection: | Springer eBooks 2005- - Collection details see MPG.ReNa |
Table of Contents:
- Background
- Palladium 1,2-migration in the Heck reaction
- Palladium 1,2-migration in the Negishi and Kumada coupling
- Stoichiometric studies on the palladium 1,2-migration
- Heteroaromatic tosylates in the regio-selective Heck reaction
- Cationic intermediates in the Ni(0)-catalyzed Heck reaction
- Carbonylative Heck reaction
- Conclusions