Multicomponent Interfacial Transport Described by the Square Gradient Model during Evaporation and Condensation

A thermodynamically consistent description of the transport across interfaces in mixtures has for a long time been an open issue. This research clarifies that the interface between a liquid and a vapor in a mixture is in local equilibrium during evaporation and condensation. It implies that the ther...

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Bibliographic Details
Main Author: Glavatskiy, Kirill
Format: eBook
Language:English
Published: Berlin, Heidelberg Springer Berlin Heidelberg 2011, 2011
Edition:1st ed. 2011
Series:Springer Theses, Recognizing Outstanding Ph.D. Research
Subjects:
Online Access:
Collection: Springer eBooks 2005- - Collection details see MPG.ReNa
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245 0 0 |a Multicomponent Interfacial Transport  |h Elektronische Ressource  |b Described by the Square Gradient Model during Evaporation and Condensation  |c by Kirill Glavatskiy 
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505 0 |a Introduction -- Equilibrium square gradient model -- Non-equilibrium continuous description -- Numerical solution for the binary mixture -- Local equilibrium of the Gibbs surface for the two-phase -- Binary mixture -- From continuous to discontinuous description -- Surface transfer coefficients for the binary mixture -- Integral relations for the surface transfer coefficients -- Conclusions and perspectives 
653 |a Heat engineering 
653 |a Physical chemistry 
653 |a Thermodynamics 
653 |a Heat transfer 
653 |a Physical Chemistry 
653 |a Chemistry, Technical 
653 |a Mass transfer 
653 |a Engineering Thermodynamics, Heat and Mass Transfer 
653 |a Industrial Chemistry 
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520 |a A thermodynamically consistent description of the transport across interfaces in mixtures has for a long time been an open issue. This research clarifies that the interface between a liquid and a vapor in a mixture is in local equilibrium during evaporation and condensation. It implies that the thermodynamics developed for interfaces by Gibbs can be applied also away from equilibrium, which is typically the case in reality. A description of phase transitions is of great importance for the understanding of both natural and industrial processes. For example, it is relevant for the understanding of the increase of CO2 concentration in the atmosphere, or improvements of efficiency in distillation columns. This excellent work of luminescent scientific novelty has brought this area a significant step forward. The systematic documentation of the approach will facilitate further applications of the theoretical framework to important problems